(1) CH4 (g) + 2 O2 (g)
CO2 (g) + 2 H2O (l)
Oxidation number of carbon in CH4 is -4
Oxidation number of carbon in CO2 is +4
change in oxidation number for carbon = final oxidation number - initial oxidation number
change in oxidation number for carbon = +4 - (-4)
change in oxidation number for carbon = 4 + 4
change in oxidation number for carbon = 8
Value of n is 8
(2) 2 NO3- (aq) + 4 H+ (aq) +
Cu (aq)
2
NO2 (g) + 2 H2O (l) +
Cu2+ (aq)
Oxidation number of copper in Cu is 0
Oxidation number of copper in Cu2+ is +2
change in oxidation number for copper = final oxidation number - initial oxidation number
change in oxidation number for copper = +2 - (0)
change in oxidation number for copper = 2
Value of n is 2
Determine the value of n in the Nernst equation for the following reactions: CH4(g) + 2...
1. Determine if each of the following reactions is a redox reaction, or is not a redox reaction. a. C4H8 (g) + O2 + H20 (g) + CO2 (g) b. HCl (aq) + NaOH (aq) → H20 (1) + NaCl (aq) c. Fe2O3 + H2 → Fe + H2O d. Cu (s) + HNO3 (aq) → Cu(NO3)2 (aq) + NO2 (g) + H20 (1) e. CzHe(g) + 5 O2 (g) → 3 CO2 (g) + 4 H20 (g)
8. Using the Nernst equation, determine the ratio of
Hg2+ to Cu2+ at equilibrium in an
electrochemical cell in otherwise pure water, when in contact with
Hg(s) and Cu (s)
Potentially useful data: Reaction Hg 2 +2e = Hgº(s) Feste = Fe2 Cu 2 +2e = Cuº(s) 2H + 2e = H2(g) Pb2 +2e=Pbº(s) Ca*2 + 2e = Cdº(s) 1/4 O2(g) + H + = 1/2 H2O 2 02(g) + 2H+ + 2e = H,O2 1/2 NO3 + H +...
Which of the following are redox reactions?
CO2(g) + 2H2O(l)
H3O+(aq) +
HCO3-(aq)
2CuS(s) + O2(g)
Cu(s) + SO2(g)
2AgNO3(aq) + Cu(s)
Cu(NO3)2(aq) + 2Ag(s)
2AgNO3(aq) +
Na2SO4(aq)
2NaNO3(aq) +
Ag2SO4(s)
CO(g) + H2O(g)
CO2(g) + H2(g)
any oxidation-reduction reactions can be balanced by i spection. Try to balance the following reactions by inspection In each reaction, identify the substance reduced and the sub stance oxidized. a. Al(s) + HCl(aq)→AICI3(aq) 12(g) b. CH4(g) + S(s) → CS2(l) + H2S(g) c. C3H8(g) + O2(g) → CO2(g) + H2O(1) d. Cu(s) + Ag+(aq) → Ag(s) + Cu2+ (aq)
Which one of the following reactions is NOT a redox reaction? A. 3 Hg(l) + 2 Cr(NO3)3(aq) → 3 Hg(NO3)2(aq)+ 2 Cr(s) B. 2Ag(s) + 2HNO3(aq) → 2AgNO3 (aq) + H2 (g) C. 2 HClO4(aq) + CaCO3(s) → Ca(ClO4)2(aq) + H2O(l) + CO2(g) D. Fe2O3(s) + 3 CO(g) → 2 Fe(s) + 3 CO2(g) E. CH4(g) + 2 O2(g) → CO2(g) + 2 H2O(l)
For each of the following reactions, balance the chemical
equation, calculate the emf, and calculate G° at 298 K. (Use the smallest possible
coefficients for H2O(l),
H+(aq), and HO-(aq). These
may be zero.)
(a) In acidic solution copper(I) ion is oxidized to copper(II)
ion by nitrate ion.
Cu+(aq)
+ NO3-(aq)
+ H+(aq) Cu2+(aq) NO(g)
+ H2O(l)
emf
V
G°
kJ
(b) Aqueous iodide ion is oxidized to I2(s) by
Hg22+(aq).
I-(aq)
+ Hg22+(aq)
+ H+ I2(s) Hg(l)
+ H2O(l)
emf
V
G°
kJ
(c) In basic solution Cr(OH)3(s) is...
Calculate ΔrH for the following reaction: CH4(g)+2O2(g)→CO2(g)+2H2O(l) Use the following reactions and given ΔrH's. CH4(g)+O2(g)→CH2O(g)+H2O(g), ΔrH = -284 kJmol−1 CH2O(g)+O2(g)→CO2(g)+H2O(g), ΔrH = -527 kJmol−1 H2O(l)→H2O(g), ΔrH = 44.0 kJmol−1
UPJ LUIS 2. Determine which of the following reactions are “redox" reactions. Circle the "letter' of only those that represent redox reactions. a. Cu + 4HNO3 = 2 NO2 + 2 H2O + 2 Cu(NO3)2 b. Zn + 2 H+ = Zn2+ + H2 C. BaCl2 + H2SO4 = 2 HCI + BaSO4 d. H+ + Br- => HBr e. 2 Fe + 3 Cl = 2 FeCl3 f. AgNO3 + HCI = AgCl + HNO3 g. 2NaOH + H2SO4...
20. Identify the neutralization reaction. Classify all of the reactions shown below. a) CH4 (g) + 2 O2 (g) → CO2 (g) + 2 H2O (l) b) MgBr2 (aq) + Cl2 (g) → MgCl2 (aq) + Br2 (l) c) HCl (aq) + NaOH (aq) → NaCl (aq) + H2O (l) d) BaCl2 (aq) + 2 AgNO3 (aq) → 2 AgCl (s) + Ba(NO3)2 (aq) 23) Calculate the mass and the number of the hydroxide ions in Ca(OH)2 required to react...
2. Determine the values of E°cell and ΔG° for the following reactions. (a) O2(g) + 4 I–(aq) + 4 H+(aq) → 2 H2O(l) + 2 I2(s) E°cell _________ ΔG°__________ (b) 4 IO3–(aq) + 4 H+(aq) → 2 I2(s) + 2 H2O(l) + 5 O2(g) E°cell _________ ΔG°_________