Question

1. Why are the alpha (α) hydrogens of an aldehyde or ketone acid? 2. How do...

1. Why are the alpha (α) hydrogens of an aldehyde or ketone acid?
2. How do you identify that in an IR spectrum there is the presence of a disubstituted in ortho position?
3. Why is benzaldehide considered a molecule with no alpha (α) hydrogens?
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Answer #1

Alpha hydrogen is the H atom attached with alpha carbon atom joined to the carbonyl group. Benzaldehyde's alpha carbon does not contain any alpha hydrogen. And for ortho substitution in aromatic rings, there is no intense ring bending peak around 690 cm-1 and rather it is completely absent. The detailed solution is given below:

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