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11. For each pair of substances determine which has the higher entropy per mole of substance....

11. For each pair of substances determine which has the higher entropy per mole of substance. a. H2O (s) at 200 K or H2O(s) at 298 K. b. H2(g) at 298 K, 2.0 atm or H2(g) at 298 K, 1.0 atm. c. H2(g) at 298 K, 5.0 L or H2(g) at 298 K, 1.0 L. d. H2(g) at 500 K, 1.0 atm or H2(g) at 298 K, 1.0 atm. e. H2O(l) at 298 K or H2O(g) at 298 K. f. O2(g) at 298 K, 1.0 atm or N2O4(g) at 298 K, 1.0 atm.

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  1. H2O (s) at 200 K or H2O(s) at 298 K.

Answer: H2O(s) at 298 K

Reason: Increasing the temperature will increase the entropy

  1. H2(g) at 298 K, 2.0 atm or H2(g) at 298 K, 1.0 atm.

Answer: H2(g) at 298 K, 1.0 atm.

Reason: A gas has higher entropy at a lower pressure.

  1. H2(g) at 298 K, 5.0 L or H2(g) at 298 K, 1.0 L.

Answer: H2(g) at 298 K, 5.0 L

Reason: The larger the volume the higher the entropy.

  1. H2(g) at 500 K, 1.0 atm or H2(g) at 298 K, 1.0 atm.

Answer: H2(g) at 500 K, 1.0 atm

Reason: Increasing the temperature will increase the entropy

  1. H2O(l) at 298 K or H2O(g) at 298 K.

Answer: H2O(g) at 298 K.

Reason: A gas has higher entropy than a liquid.

  1. O2(g) at 298 K, 1.0 atm or N2O4(g) at 298 K, 1.0 atm.

Answer: N2O4(g) at 298 K, 1.0 atm

Reason: More will be the gaseous components more will be entropy

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