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Consider the BF3 molecule. There are SALCs from the F valence orbitals which transform as A2”...

Consider the BF3 molecule. There are SALCs from the F valence orbitals which transform as A2” and E”. Are there any valence orbitals of the central B atom that can have a non-zero overlap with these SALCs? How would your conclusion differ for AlF3 where 3d orbitals might be available?

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