12) The rate of the elementary reaction
has been studied as a function of temperature between
1500 and 2100 K. The following
data were obtained for the rate constant k:
| Temperature (K) | k (L mol-1 s-1) |
|---|---|
|
1500 |
2.18×104 |
|
1620 |
4.82×104 |
|
1740 |
9.57×104 |
|
1860 |
1.74×105 |
(a) Calculate the activation energy of this reaction. ___ kJ
mol-1
(b) Calculate the factor A in the Arrhenius equation for the
temperature dependence of the rate constant. ___ L mol-1
s-1
12) The rate of the elementary reaction CS2 + O2 ---> CS + SO2 has been...
The rate of the elementary reaction
C2H2 +
O2C2H
+ HO2
has been studied as a function of temperature between
300 and 2500 K. The following
data were obtained for the rate constant k:
Temperature (K)
k (L mol-1 s-1)
300
6.25×10-45
740
1.19×10-12
1180
1.91×10-4
1620
1.07
(a) Calculate the activation energy of this
reaction. kJ mol-1
(b) Calculate the factor A in the Arrhenius equation for the
temperature dependence of the rate constant. L
mol-1 s-1
a) Given these data for the reaction , write the rate-law expression. (Use k for the rate constant.) Rate = _______ The specific rate constant = ___________ Expt. Initial [A] (M) Initial [B] (M) Initial Rate of Formation of C () 1 0.15 0.40 4x10^-5 2 0.15 0.80 1.6x10^-4 3 0.30 1.6 1.3x10^-3 b) The rate of the elementary reaction C2H2 + H2->C2H4 has been studied as a function of temperature between 300 and 2500 K. The following data were...
3. You are given the following data for the following reversible reaction that is considered elementary. It is a gas phase reaction. CS2 + 4H2 → CH4 + 2H2S k (dm2/mol** min) T(°C) 145.31 500 336.95 719.57 600 1451.33 650 2796.97 700 9282.64 800 550 What are the values for the Arrehenius equation? Make sure to carry numbers at least six digits past the decimal when using temperature and at least four digits past the decimal when using the reaction...
There are several factors that affect the rate of a reaction. These factors include temperature, activation energy, steric factors (orientation), and also collision frequency, which changes with concentration and phase. All the factors that affect reaction rate can be summarized in an equation called the Arrhenius equation: k=Ae−Ea/RT, where k is the rate constant, A is the frequency factor, Ea is the activation energy, R=8.314 J mol−1 K−1 is the gas constant, and T is the absolute temperature. A certain...
There are several factors that affect the rate of a reaction. These factors include temperature, activation energy, steric factors (orientation), and also collision frequency, which changes with concentration and phase. All the factors that affect reaction rate can be summarized in an equation called the Arrhenius equation: k=Ae−Ea/RT, where k is the rate constant, A is the frequency factor, Ea is the activation energy, R=8.314 J mol−1 K−1 is the gas constant, and T is the absolute temperature. A certain...
Consider the homogeneous reaction between sulfur vapor and methane to form carbon disulfide This elementary reaction has been studied experimentally in a small tubular reactor with a 35.2 cm3 volume. In a particular steady state run at 600 °C and 1 atm, a total of 1.32 mmol of CS2 were collected from the reactor outlet during 10 min of operation. The feed consisted of 4 mmol of S2/min plus a stoichiometric amount of CH4 Find the rate constant (k) for...
1) The rate constant for the reaction 2 N,Os(9) = 4 NO (9) + O2(9) is reported in units of sl. What is the overall order of the reaction? 2) The rate law for a reaction was reported as rate=k[A] [B][C] with molar concentrations in moles per cubic decimetre and time in seconds. What are the units of k? 3) The rate constant for the pseudo first-order acid- catalysed hydrolysis of glucose is 4.07' 10-s. Calculate the half-life for the...
The elementary reaction 2NO2 (g) -> 2NO (g) + O2 (g) is second order in NO2 and the rate constant at 660 K is 5.23 M-1s-1. The reaction half-life at this temperature when [NO2]0 = 0.45 M is ____ s.
5. An elementary reaction has the form 2A → B. The rate law is Rate A) k[A] B) 2 k[A] C) k? [A] D) k[A] 6. For some reaction, when concentration of reactant "A" doubles, the rate of the reaction doubles. The reaction is order in reactant A. B) 1" A oth C) 2nd D) 3rd 7. Tetrahydrofuran (commonly referred to as THF) is an organic solvent with a density of 0.889 g/mL. A solution is prepared by dissolving 11.8...
The production of methyl bromide is an irreversible liquid-phase reaction that follows an elementary rate law. The reaction CNBr (A) + CH3NH2 (B)àCH3Br (C) + NCNH2 (D) is carried out isothermally in a semi-batch reactor. A solution of methylamine (B) in extra dry ethanol at a concentration of 0.025 mol/L is to be fed at a rate of 0.05 L/s to an solution of bromine cyanide (A) in extra dry ethanol contained in a glass-lined reactor. The initial volume of...