. Write the formula and name for the product when cyclohexene re-acts with
(a) Br2
(b) HI
(c) H2O, H+ (
d) KMnO4(aq) (cold)
. Write the formula and name for the product when cyclohexene re-acts with (a) Br2 (b)...
3. An unknown with Br2 or cold KMN04, Reaction of 'X' witl th formula CaH1Br does ly one product 'Y with the formula CsH10. "Y reacts with Brs or cold KMNO4. Y' also react with 03 and (CH3)2S to give CaHio02. Draw the structural formulas for X, Y, and Z. (6 points) the following three compounds in the order of increasing acidity (6 points). I. A 5. Name the following compounds using IUPAC nomenclature (8 points) Br b)
3. An...
write a major product for each of the following reaction,
indicate appropriate stereochemistry
1. Br2, hv (a) 2. NaOCH3, Cн,Он, Д 1. x's NaNH2 3. KMnO4, H30 X, cold (c) .CI 2. Br Br 3. K, NH3(), CH3CH2OH 4. CHCI3 NaOH(aq) 1. H2SO4 Он (b) 2. CH3COOOH 3. Нао х
11. Write out the structural formula of the product for the following reactions. (20 pts) (a) H2O H (b) 1) BH; 2) H2O2, NaOH (c) Br2 (2 moles) (d) H2 Lindlar catalyst (e) HO H, Hg?
each a. 3-methyl-2-pentene b. cyclohexene с. propene 1.64 Give the name for the product from the hydrogenation of ead of the following: (11.7) a. 1-hexene b. 2-methyl-2-pentene cyclopropene 65 Draw the condensed structural or line-angle formula for the product of each of the following: (11.7) 19 Ni + H2 a. + H.O H b. mula for the 66 Deaw h.
of the product in each 11.14 Draw the condensed structural formula of the product of the following reactions: H a. CH3-CH-CH=CH2 + HOH b. cyclohexene + H,"> o b olno c. cis-2-butene + Br2 CH3 d. CH3 -CH-C=CH + 2H2 CH3 e. CH3-C=CH-CH2-CH3 + H, P, H.
Write the structural formula and name of the organic product for
the following reaction between an alkyne and an alkyl halide. (The
alkyne group is shown, and should be entered, as "CC", without the
triple bond.)
(A.) Product structural formula (formating counts: enter C
before associated H atoms; subscript numbers) (e.g.,
CH3CH2CH2OCHCHCH3)
(B.) Product name:
Write the structural formula and name of the organic product for the following reaction between an alkyne and an alkyl halide. (The alkyne group is...
1. Complete the following reactions, with the major organic product. a. CH3-CH=CH2 + Br2 O + B12 c. CH3-CH-CH-CH3 +KMnO4+H2O d. CH3CH2-CH=CH-CH2CH3 + H2S04 2. Between hexane, cyclohexene and toluene, which was the most reactive with bromine solution? Explain your reasoning. 3. Based on the chemical tests used in this experiment, is it possible to clearly distinguish between alkanes and alkenes? Explain your reasoning. P
Complete the following reaction equations (Hint for b and c: Markonikov’s Rule applies; reaction in e refers to oxidation) a. CH3(CH2)2CH=CH2 + Br2 -->?? b. CH3CH2C(CH3)=CHCH3 + HI -->?? c. CH3CH2CH=CH2 + H2O (in the presence of H+) --> ?? d. C6H5-CH=CH2 + H2 (in the presence of Pt @ 25o C and 1 atm) -->?? (note: C6H5 = benzene ring) e. CH3CH=CHCH3 + KMnO4 (in the presence of H2O; cold) --> ??
10. Write ONLY the MAJOR product(s) for the following reactions: A-C 3 pts each and D-F are 5 pts each (24 pts) BH3 (Show product(s) with sterochemistry) D OH, H2O2 Cold KMnO4, OH/H,0 (Show product(s) with sterochemistry) E Br2 F (Show product(s) with sterochemistry) CCL
subsrate cyclohexanol
product cyclohexne
THE SYNTHESIS OF CYCLOHEXENE 1. Write a balanced equation (using structural formula for substrate and product) for this reaction including reaction conditions on arrow. (1 mark)