1 – Balance the following
2 – Describe the basic features of a galvanic cell and explain why the two components are separated from each other.
3 – Calculate the standard potential of a cell that uses a Mg/Mg2+ half-cell and a Cu/Cu2+ half-cell. Identify the oxidizing agent.
4 – What is the equilibrium constant for the cell referenced in problem 3?
5 – If a hydrogen fuel cell runs an electric motor drawing a current of 8.5 A for 3.0 h, what volume of H2(g) is needed if the fuel is stored at 155 atm and 25 °C? (Ideal gas law required. Assume H2 behaves as an ideal gas under these conditions.)
6 – Chromium plating can be applied by electrolysis to objects according to the following unbalanced half-reaction:
Cr2O72- + e- + H+ → Cr(s) + H2O
How long (in hours) would it take to apply a chromium plating 0.010 mm thick to a car bumper with a surface area of 0.25 m2 in a cell with a current of 25.0 A? The density of chromium is 7.19 g/cm3.
Balance the following redox equations by the half-reaction method: (a) Mn2+ + H2O2 → MnO2 + H2O (in basic solution) (b) Bi(OH)3 + SnO22− → SnO32− + Bi (in basic solution) (c) Cr2O72− + C2O42− → Cr3+ + CO2 (in acidic solution) (d) ClO3− + Cl− → Cl2 + ClO2 (in acidic solution) (e) Mn2+ + BiO3− → Bi3+ + MnO4− (in acidic solution)
5 – If a hydrogen fuel cell runs an electric motor drawing a current of 8.5 A for 3.0 h, what volume of H2(g) is needed if the fuel is stored at 155 atm and 25 °C? (Ideal gas law required. Assume H2 behaves as an ideal gas under these conditions.) 6 – Chromium plating can be applied by electrolysis to objects according to the following unbalanced half-reaction: Cr2O72- + e- + H+ → Cr(s) + H2O
16.52 Balance each of the following unbalanced equations for cell reactions in acidic conditions, then calculate the standard cell emf, and decide whether the equation is written in the direction of spontaneous reaction. (a) Sn2+ (aq) + Ag(s) > Sn(s) + Ag+ (aq) (b) Al(s) + Sn4+ (aq) → Sn²+ (aq) + AP+ (aq) (C) CIO3+ (aq) + Ce3+ (aq) —Cl(aq) + Ce++ (aq) (d) Cu(s) + NO3 (aq) —> Cu2+ (aq) + NO(g) 16 .1 APPENDIX F standard Reduction...