what is value of Free radical copolymarasation reactivity ratio(propylene-nitroethylene)?
Ans:
The Free radical co polymerisation reactivity ratio fo Propylene - Nitroethylene is
* r1 = 0.005
* r2 = 31
Cp2 Zr Me2
Propylene -----------------------------> Nitro ethylene
The Catalyst used in this rection is Ziegler - Natta catalyst
what is value of Free radical copolymarasation reactivity ratio(propylene-nitroethylene)?
5. Use the ratio of 1-chloro- to 2-chloropropane obtained from free-radical chlorination ) to calculate the intrinsic reactivity difference between a primary and secondary (44:56 hydrogen atom of propane. Use the information to predict the expected ratio of 1-chloro- to 2-chlorobutane. Cl hv 44 :56
Draw all the products resulting from the free radical chlorination of 2,4-dimethyl pentane, and predict the relative product distribution. Assume a ratio of 5.5 : 3.75 : 1.0 for the relative reactivity of tertiary to secondary to primary hydrogens in the free radical chlorination of unsubstituted alkanes. Express final ratio of products as a percent (total should add up to 100).
The experiment of free radical stability.4.0ml of dichloromethane was added to each four 13 *100mm test tubes.to each test tube 1.0ml of a different aromatic hydrocarbon-toluen,ethylbenzene,isopropylbenzene and t-butylbenzene and swirl to mix.under the hood 1.0 M bromine in dichloromethane to each test tube.time was also recorded after addition of bromine,2 minutes,35 seconds. 20 seconds and 14 minutes respectively.1.arrange the four hydrocarbons in order of their reactivity towards bromine,most reactive first and compare with the results.2.write a balanced equation for each...
What is the difference between coordination polymer and free radical ?
19) When 2,2-dimethylbutane is subjected to free-radical chlorination, _distinct monochlorinated products are possible and of these contain asymmetric carbon atoms. A) 4,2 B) 5,0 C) 3,0 D) 5,2 E) 4,0 20) Arrange the substrates in order of increasing Sn2 reactivity with NaCN: Bromoethane, 1-chloro-3,3-dimethylpentane, 1-chloro-2,2-dimethylpentane, and 2-bromo-2-methylpentane. 21) Arrange the following compounds in order of increasing reactivity toward ethanol solvolysis: t-butyl bromide, l-butyl iodide, isopropyl chloride, and methyl iodide.
What is the order of reactivity by brominating isopropyl benzene, ethyl benzene, toulene, methylcyclohexane, cyclohexane, tertbutyl benzene. Discuss if the order of reactivity was similar to what was predicted based on radical stability. Also discuss reasons why one of the hydrocarbons would react faster than another based on radical stability
11) The table compares the reactivity of alkanes and alkenes with chlorine. alkanes alkenes name of the type of reaction with chlorine substitution addition and substitution name of the type of reacting species free radical electrophile and free radical (6) During the first stage in the substitution reaction chlorine forms chlorine free radicals Explain what is meant by the term free radical. [1] (1) Name and explain the type of bond breaking which occurs to form chlorine free radicals .....
A pair of monomers M1 and M2 undergoing radical chain copolymerization were found to have reactivity ratios r1 = 0.1 and r2 = 10.0. What is the composition of the initial copolymer that is formed when the monomer feed contains (a) an equimolar amount of M1 and M2 and (b) 2 moles of M1 per mole of M2? Show how you arrived at your answers.
Free- radical halogenation of alkanes. What are the 5 possible products of (CH3)2CHCH2CH2CH3?
The free-radical polymerization of ethylene is spontaneous. What is the sign of entropy change in this process? Describe whether the polymerization reac- tion is exothermic or endothermic. Explain.