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Explain the thermodynamic underpining principles and the processes occuring at a molecular level for these two...

Explain the thermodynamic underpining principles and the processes occuring at a molecular level for these two experiments:

1. A mixture of triethylamine-water, which was partially miscible at room temperature, and it became miscible after cooling.

2. A mixture of Hexane-Nitrobenzen was at one phase at high temperature, but became partially immiscible when cooling.
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