Be sure to answer all parts. The pH of a 0.30 M solution of a weak base is 10.02. What is the Kb of the base? Kb = × 10
Let us consider weak base be BOH
BOH(aq) -------> B+(aq) + OH-(aq)
pH + pOH = 14
pOH = 14-10.02 = 3.98
pOH = -log [OH-] = 3.98
[OH-] = 10-3.98 = 0.000105 M
BOH(aq) -------> B+(aq) + OH-(aq)
Initial Concentration : 0.3 0 0
Change in concentration :(0.3-0.000105) +0.000105 +0.000105
Equilibrium concentration : 0.299895 0.000105 0.000105
Kb = [OH-] [B+]/[BOH] = (0.000105)2/0.299895 = 0.000000011/0.299895 = 3.67 X 10-8
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