(1) The reaction the decomposition of ammonia is shown below. Calculate the total ∆H If bond energies in K/J: N≡N is 944, H-H is 436 and N-H is 388 Reactions: 2 NH3→N_2+3H_2 Explain reason for your answer
(2) Which of the following statements is FALSE and why?
A) Entropy is a state function.
B) Endothermic processes decrease the entropy of surroundings, at constant T and P.
C) Endothermic processes are never spontaneous.
D) Entropy of the surroundings depends on the enthalpy of the system at a constant T.
E) None of the above
(3)
Identify the change in state that does not have an increase in entropy explain reason for your answer.
(A) Vaporization
(B) Sublimation
(C) Dissolving
(D) Deposition
(E) Melting
(4) Calculate ∆G° for the reaction below from
formation value given and explain reason for your answer
2NaCI (s) →2Na(s)+CI2(g)
∆Gf° NaCl (s) =-384 KJ/MOl
(5) Which statement is True and why?
a) An exothermic reactions absorbs heat from the surroundings.
B) Enthalpy is the sum of a system’s internal energy and the product of pressure and volume.
C) ∆Grxn is the entropy of reaction.
D) ∆Grxn is a measure of heat.
E) Endothermic relation have a negative sign for ∆H
CHEMISTRY
(1) The reaction the decomposition of ammonia is shown below. Calculate the total ∆H If bond...
1a. Using bond dissociation energies, calculate the heat of
reaction (ΔH) for the reaction
shown below. Show all your work and provide a reference for where
you got your bond
dissociation energy values.
1b. Is this reaction endothermic or exothermic? Explain. Provide
energy diagrams
showing the two processes. Circle the one that corresponds to this
reaction. Label the axis
appropriately as well as the activation energy (Ea).
la. Using bond dissociation energies, calculate the heat of reaction (AH) for the...
1. The dimensions of the SI unit of energy, the Joule (J), are A. K B. kg m s C. kg m2 s-2 D. kg m-1 s-2 E. kg m2 s-1 2. Natural gas, or methane, is an important fuel. Combustion of one mole of methane releases 802.3 kilojoules of energy. How much energy does that represent in kilocalories? A. 3.36×103 kcal B. 3.357 kcal C. 191.8 kcal D. 0.192 kcal E. 1.918×105 kcal 3. What is the change in...
Pre-lab Study Questions 1. Calculate the enthalpy of reaction DHrxno for each of the following reactions using the tabulated standard enthalpy of formation DHfo. (Show calculation) a. H2O(g) ® H2O(l) b. CaCO3(s) ® CaO(s) + CO2(g) c. CH4(g) + 2 O2(g) ® CO2(g) + 2 H2O(g) 2. Consider the following reaction and the given standard enthalpy of formation DHfo. NH4NO3(s) ® NH4+(aq) + NO3-(aq) DHfo (kJ/mol) -365.6 -132.0 -205.0 a. Calculate the enthalpy of reaction DHrxno for the above reaction...
1) A chemical reaction and a table of bond dissociation energies are shown below. H3C H НАС + H2O HOZCHz H2C H acid HzC catalyst Bond BDE (KJ/mol) Bond BDE (KJ/mol) Csp3-H 410 Csp2-Csp2 sigma 418 Csp2-H 427 Csp2-Csp2 pi 264 Csp-H 523 C-O sigma 355 Csp3-Csp3 368 C-O pi 261 Csp2-Csp3 418 HO-H 460 a) Calculate the enthalpy change (AH) for the reaction. Remember to include the sign and units. b) If you touched the outside of the reaction...
33. The following scheme depicts what type of chemical reaction? Page 5 H Η Ο Iran no ranom.don -- [ H-NCH27, N-H + 1 HOCCH27; COH Diamine Adipic acid tN(CH)N-C(CH2),C7,+ 2n H,O Nylon 6,6 A) Addition polymerization C) Condensation polymerization E) Elastomeric polymerization B) Acid-base reaction D) Ionic polymerization 34. The phase changes BC and D E are not associated with temperature increases because the heat energy (q) is consumed to A) increase distances between molecules B) break intramolecular bonds...
10. Use the following information to determine the enthalpy for the reaction shown below CH_g) + H-0(g) - CO(g) + 3H48) AH-? 2C(s) + 2H2O(g) - CHig)+CO ) Nf - 153 C) + HẠO - COR) + Hg) M - 1313 CO(g) + HO(g) + COMg + Hg) N - -41 2 kJ 11. In the energy diagram shown here, label parts A through E and state if the diagram repre- sents an endothermic or exothermic reaction. Energy Reaction coordinate...
10. Given the thermochemical data below, what is the change in enthalpy when 10.0 g of H, are reacted? N; (g) + 3H2(g) → 2NH, (g): AH = -91.2 kJ (A) -452 kJ (B) +452 kJ (C) -151 kJ (D) -1357 kJ 11. Which of the following is NOT a state function? 1. Heat 2. Change in enthalpy 3. Change in internal energy 4. Change in pressure (A) 1 only (B) 2 only (C) 2 and 3 (D) 1 and...
NEED HELP ASAP 1-4
and has a question. 1) A chemical reaction that releases heat to the surroundings is said to be _AH at constant pressure. A) endothermic, positive B) endothermic, negative C) exothermic, positive D) exothermic, neutral E) exothermic, negative kJ of heat are transferred when 161.8 2) The value of AHº for the reaction below is -72 kJ. g of HBr is formed in this reaction. H2(g) + Br2 (g) → 2HBr (g) A) 54 B) 36 C)...
21C.1(a) The reaction of propylxanthate ion in acetic acid buffer
solutions
has the mechanism A− +H+→P. Near 30 °C the rate constant is given
by the
empirical expression kr=(2.05×1013) e−(8681K)/T dm3mol−1 s−1.
Evaluate the
energy and entropy of activation at 30 °C.
21C.1(b) The reaction A− +H+→P has a rate constant given by the
empirical
expression kr=(6.92×1012)e−(5925K)/T dm3mol−1 s−1. Evaluate the
energy and
entropy of activation at 25 °C.
Please explain why they calculated H=E-RT like that
like why is...
QUESTION 9 If two reactions are coupled, then 2. A product of one reaction is a reactant of the other, and the overall process is product-favored. b. A product of one reaction is a reactant of the other, and the overall process is reactant-favored C. The heat released from an exothermic reaction is used in an endothermic reaction. The Gibbs free energy released from a product-favored reaction is released to the surroundings. causing an increase in entropy for a second...