Liquid ammonia autoionizes like water:
2NH3 (l) --> NH4+(am) + NH2-(am)
where (am) represents solvation by ammonia. At the boiling point (-33oC), Kam = 5.1 x 10 -2. Calculate [NH4+] at this temperature. (enter in scientific notation)
Liquid ammonia autoionizes like water: 2NH3 (l) --> NH4+(am) + NH2-(am) where (am) represents solvation...
Be sure to answer all parts. Liquid ammonia autoionizes like water: 2NH3() - NH,*(am) + NH, (am) where (am) represents solvation by ammonia. At the boiling point (-33°C), Kam = 5.1 x 10-27. Calculate [NH,+ ) at this temperature. [nu,"]=1 x 10 M (Enter your answer in scientific notation.) k Prey 3 of 3
Ammonia react with water as shown in the following equation: NH3(aq) + H2O(l) NH4+(aq) + OH-(aq) Kb = 1.77 x 10-5 and Ka = 5.65 x 10-10 a) Calculate the pH of the 0.030 M NH3 solution (Use a labeled ICE table) b) Calculate the pH of the solution at the equivalent point (when equal amount of acid is added. Assume the volume doubles). (Use a labeled ICE table) c) Over which pH range (actual numbers) do you expect...
The rate law for the reaction NH4+(aq) + NO2−(aq) → N2(g) + 2H2O(l) is given by rate = k[NH4+][NO2−]. At a certain temperature, the rate constant is 3.80 × 10−4 /M·s. Calculate the rate of the reaction at that temperature if [NH4+] = 0.261 M and [NO2−] = 0.160 M. × 10 M/s Enter your answer in scientific notation.
Liquid water at 95°C and at l atm flows through a heated pipe at a flow rate of 3.2 kg/s. It then leaves the pipe as steam. The water receives 10333440 J of heating from the pipe. Calculate the temperature of the steam leaving the pipe. Take 0°C as the reference with zero enthalpy. The boiling point at the pressure of the system is 100°C. Thermal properties: Cp of liquid water: 4200 J/kg.K Cp of steam: 1800 J/kg.K Enthalpy of...
Quest. 4 (15 pts). Ammonia react with water as shown in the following equation: NH3(aq) + H2O(l) NH4+(aq) + OH(aq) Kb = 1.77 x 10-4 and Ka = 5.65 x 10-10 a) Calculate the pH of the 0.030 M NH solution (Use a labeled ICE table) b) Calculate the pH of the solution at the equivalent point (when equal amount on added. Assume the volume doubles). (Use a labeled ICE table) c) Over which pH range (actual numbers) do you...
Mass transfer questions.
QUESTION 2 [20 MARKS] Ammonia (A) - water (B) solution is in contact at a surface with an organic liquid at 278 K. The concentration of ammonia in the organic phase is 10 wt%, and the density of aqueous solution is 961.7 kg/m². Meanwhile, the concentration of ammonia in water at the other end of the film at 5.4 mm away is 2.5 wt%, and the density is 991.7 kg/m². The flux of ammonia and the water...
Ethanolamine, C2H7NO, is a clear, viscous, hygroscopic liquid with an ammonia-like odor. It is used to remove CO2 and H2S from natural gas but it is also found in polishes, hair waving solutions, and in emulsifiers (often in pharmaceuticals). Overexposure to this compound can cause irritation to the eyes, skin and respiratory system as well as lethargy. If a 0.25M solution of this compound is found to be 125 % ionized, determine the Kb and the Ka for this substance....
Q6(a) The equilibrium distribution of ammonia between air and water at low concentration at a particular temperature is y = 1.2 x. At a certain point Page 3 of 5 in a mass transfer device, the concentration of solute A in the bulk air is 0.04 (mass fraction) and that in the bulk aqueous phase is 0.025(mass fraction). The individual mass transfer coefficient for the transport of A in the gas phase and liquid phase are ky = 7.5 kmol/m²h...
1. What is the boiling point of a 3.0 m Ca(NO3)2 solution in water? Where: the change in boiling point (ΔTb) = mKb m is the molality of the solution Kb (the boiling point constant) for water is 0.512 2. The freezing point of ethanol (C2H5OH) is -114.6 °C. What is the freezing point (°C) of a solution prepared by dissolving 50.0 g of glycerin a nonelectrolyte) in 200.0 g of ethanol? Where: ΔTf = mKf The molal freezing point depression...
Be sure to answer all parts. Carbon disulfide, a poisonous, flammable liquid, is an excellent solvent for phosphorus, sulfur, and some other nonmetals. A kinetic study of its gaseous decomposition reveals these data: Experiment Initial (CS2] (mol/L) Initial Rate (mol/L's) 1 0.100 2.7 x 10-7 2 0.080 2.2 x 10-7 0.055 1.5 x 10-7 0.044 1.2 x 10-7 (a) Choose the rate law for the decomposition of CS2. Rate = Ok k[CS2] k[CS21 k[CSI (b) Calculate the average value of...