Some electrons are close to their atomic nucleus,
others are farther away.
Which ones have more potential energy?
Answer: the electrons , those are farther away from nucleus have more potential energy than those electrons which are nearer to the nucleus.
Detailed explanation is given below
explanation: The electrons which are farther away from nucleus are weakly held by nucleus and they can be removed easily by the minimum loss of energy. Therefore they have much higher energy in compare of those electrons which are tightly held by nucleus I.e. nearer electrons to nucleus.
Also,
The coloumbic interaction energy is numerically equal to = -Ze^2/4π€r
But e = charge on electron, €= permittivity ,r= distance between electron and nucleus etc..
Thus electron which are far away have smaller 1/r and so this energy term is less negative ( and thus larger)
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