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Which one of the following procedures would result in a buffer with pH close to 9.0?...

Which one of the following procedures would result in a buffer with pH close to 9.0?
Ka(CH3COOH) = 1.8 × 10-5
Kb(NH3) = 1.8 × 10-5

Mixing 1 mol CH3COOH and 1 mol NH3 in a 1.0 L aqueous solution.

Mixing 1 mol CH3COOH and 1 mol NaOH in a 1.0 L aqueous solution.

Mixing 1 mol NH3 and 0.5 mol HCl in a 1.0 L aqueous solution.

Mixing 1 mol CH3COOH and 0.5 mol NaOH in a 1.0 L aqueous solution.

Mixing 1 mol NH3 and 1 mol HCl in a 1.0 L aqueous solution.

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