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The dreaded rock problem. An ICP experiment was performed to find the concentration of copper in...

The dreaded rock problem. An ICP experiment was performed to find the concentration of copper in
a rock (3.1416 g). The rock was ground up and reacted with 40 mL of concentrated nitric acid to dissolve all the
copper. The solution was diluted 1:1000 (let’s call this solution R) and gave an emission signal intensity of
46582.9 (arbitrary units). Then a 50 mL aliquot of solution R was mixed with 5 mL of a 16.4 ppm Cu solution and
diluted to 100 mL (let’s call this solution S). Solution S gave an emission signal intensity of 70159.3.
a. What is the concentration of Cu in solution R?

b. What is the mass of Cu in the rock?

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