three best resonance forms, indicate their relative stability(-1 for most stable) Ties are possible
OHCHNH2+
H(CO)CH(CO)H-
three best resonance forms, indicate their relative stability(-1 for most stable) Ties are possible OHCHNH2+ H(CO)CH(CO)H-
east stable most stable The following are three examples of the relative stability of carbocations in your answer to question 2. Each of these reactions should show a relatively stable carbocation intermediate. (a) The two-step reaction of 1-methylcyclohexene with HBr follows the Markovnikov 3. rule. (b) Choose 1-butanol or tert-butyl alcohol to undergo a 3-step reaction with HBr to form the alkyl bromide. The second step is the S1 formation of a carbocation. (c) Show the one most stable resonance...
3. For a) [CH3CH2C(-O)CH2l b) [CH3NHCHCHCH21 1) Draw their possible resonance forms as the Line-Angular structure. 2) Predict the product of the acid-base reaction between more stable resonance forms. Use the curved arrow to show the movement of electrons 3) Predict the product of the acid-base reaction between less stable resonance forms. 4) After comparing the reaction mechanisms and its products of 2) and 3). describe your opinion on the difference of stability of product.
3. For a) [CH3CH2C(-O)CH2l b)...
5. Arrange the following carbocations in order of decreasing stability. Draw ali possible resonance forms for each of them CH-cH-CHs+ CH CH+ CH3CH2+ CH-CH-CH-CH-CHt riate resonance Draw all resonance forms and a representation of the a hybrid for each of the foHowing s CH Rank the following six molecules in approximate order of decreasing Sl reactivity and decreasing Sx2 reactivity SN1 (decreasing->) Sw2 (decreasing→)
(9 points) 1. In each case, draw all reasonable resonance forms. Circle the most stable (plus any ties). (a) (b) (1 pt) 2. For the following Diels-Alder reaction, label the Endo and Exo products. Circle the major product.
(9 points) 1. In each case, draw all reasonable resonance forms. Circle the most stable (plus any ties). (а) o CH3-N CH3 CH3 (b) (c) (1 pt) 2. For the following Diels-Alder reaction, label the Endo and Exo products. Circle the major product Н CO2CH3 .CO2CH3 + + CO2CHS н
Arrange the following weak bases in order of expected increasing stability. H CH CH3 H-C-H HC-N-CH, HỌC-C-CH, * *0 II III a. (least stable base) III <I < II (most stable base) b. (least stable base) I < II < III (most stable base) c. (least stable base) III <II < I (most stable base) d. (least stable base) I III < II (most stable base) e. (least stable base) II < 1 < III (most stable base) f. (least...
Which of the following compounds is more stable? or A B A They have same stability B Onto which of the numbered atoms in this structure can the negative charge be moved by resonance delocalization? 8 4 5 3 7 HC 2 co 1 2, 4, 6 only 1, 3, 5, 8 only 1, 3, 5 only 2, 4, 6, 7 only Which Newman projection represents the most stable conformation of the following compound when viewed down the 2-3 carbon-carbon...
ch 22
Draw the most stable resonance form for the intermediate in the following electrophilic substitution reaction. In progress OCH OCH3 CH3CI / AICI: HC • You do not have to consider stereochemistry • Include all valence lone pairs in your answer . In cases where there is more than one answer, just draw one С P he (1 (Review Topics (References Draw the most stable resonance form for the intermediate in the following electrophilic substitution reaction. CHE -CH₂ CH,CI...
11. Indicate the order of stability CH н сн. Br CH сH, На н н. Br H H н н" Br н H н н н' Br н A В C D 12. Which of the following structures does NOT have tetrahedral geometry around any of its central central atoms. Use resonance to help explain A. В. с. D. = NH2 13. Is it theoretically possible to separate the pair of compounds below by distillation? Explain briefly CH CHs Br...
1. Draw all the significant resonance forms for the following structures, and indicate which are major and which are minor, or if you have two equally important forms, say so. The number of new forms you need to draw is shown in parentheses below the arrow. (a) N co 4. In each of the following reactions, indicate which structure is the nucleophile and which is the electrophile. Also draw the products (use the electron pair arrows to guide you). (a)...