A cation-sensitive electrode displays a (referenced) potential of 209.6 mV in a 0.0123-M CaCl2 solution.
Calculate the ionic strength of the above solution.
μ =
Use the extendeded Debye-Huckel equation to calculate the activity coefficient of the calcium ion in this solution, at 25°C? logγ=−0.51Z2μ√1+αμ√305
Where α = 600 pm (for Ca2+).
γCa2+ =
Calculate the activity of Ca2+ in this solution.
aCa2+ =
A cation-sensitive electrode displays a (referenced) potential of 209.6 mV in a 0.0123-M CaCl2 solution. Calculate...
Activity Calculate the activity coefficient, y, of Fe2+ when the ionic strength of the solution, μ , is 0.074 M lonic Strength Coefficient 2+ (a) by linear interpolation of the data in the table to the right; 0.001 0.005 0.01 0.05 0.1 0.870 0.749 0.675 0.485 0.405 Number Fe (b) by using the extended Debye-Huckel equation at 25°C, where the ion size is 600 pm Number Fe
A. Calculate the ionic strength of 0.16 M Al2(SO4)3. B. If a calcium ion selective electrode immersed in 0.1 M CaCl2 reads +40 mV, what should the potential be in 1.0 M CaCl2?
Calculate the activity coefficient, ?, of Cu2 when the ionic
strength of the solution, ? , is 0.078 M:
(a) by linear interpolation of the data in the table to the
right;
yCu2+ = 0.440
(b) by using the extended Debye-Huckel equation at 25°C, where
the ion size is 600 pm.
yCu2+ =
answer to part a is correct.
ionic strength (,M)
activity coeffient
Cu2+
0.001
0.870
0.005
0.749
0.01
0.675
0.05
0.485
0.1
0.405
Calculate the activity coefficient, γ, of Sn2+ when the ionic strength of the solution, μ, is 0.059 M by linear interpolation of the data in the table. Ionic strength (μ, M) Activity coefficient (γSn2+) 0.001 0.870 0.005 0.749 0.01 0.675 0.05 0.485 0.1 0.405 γSn2+= Calculate the activity coefficient, γ, of Sn2+ when the ionic strength of the solution, μ, is 0.059 M by using the extended Debye-Hückel equation at 25 °C, where the ion size is 600 pm. γSn2+=
PHARMACEUTICS CLASS Question 1: The activity of sodium ions in a 0.10 M solution is 0.079M. What percentage of ions in this solution is free? Write numerical answer only; round to nearest percentage. Question 2: Calculate the ionic strength of a solution that contains 0.184 M NaCl, 0.318 M CaCl2, 5% w/v dextrose (mw = 180.16 g/mol), and 0.021 M FeCl3. Report answer to three decimal places (with leading zeros as appropriate). Do not type units into answer field (assume...