8) [5 pts] How do you determine if a coordinated NO ligand is L-type or X-type?...
8) [5 pts] How do you determine if a coordinated NO ligand is L-type or X-type? Describe at least two methods you can use. You may need to use other resources besides the text
Homework Answers
Linear and Bent nitrosyl possible ligands, ( metal ligand : M-N-O )
ligands can be distinguished
(1) Infrared spectroscopy : Linear M-N-O groups absorb in the range of 1650-1900 cm-1 , whereas bent nitrosyls absorb in the range 1525–1690 cm−1. Both having different NO bond orders for linear (triple bond) and bent NO (double bond).
(2) Enemark-Feltham notation : From here we determines different bent and linear NO ligands is the sum of electrons of pi-symmetry. The bent NO ( η1) ligand is sometimes described as the anion, NO− and The linear NO ( η3) ligand is sometimes described as the cation, NO+
eg. [ CpMo(PPh3)3NO] complex 18 electron system so NO must be bent η1
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8) [5 pts] How do you determine if a coordinated NO ligand is
L-type or X-type?...
5. Professor Karl von Fildenshmirtzen is studying a transition metal ligand exchange reaction as follows below...
5. Professor Karl von Fildenshmirtzen is studying a transition metal ligand exchange reaction as follows below and is attempting to determine whether or not the mechanism is associative or dissociative (RDS rate-determining step): Dissociative X RDS + Associative L RDS X + a. Describe how Professor Fildenshmirtzen may distinguish between these two mechanisms using an Eyring plot. b. The AS for the reaction was determined to be negative. Which mechanism is operative?
Could you show how to do (d) step by step, please? AO = Atomic orbital MO = Molecular orbital (L)GO= (Ligand) Group orb...
Could you show how to do (d) step by step, please?
AO = Atomic orbital
MO = Molecular orbital
(L)GO= (Ligand) Group orbital
2. TaHs has a square pyramidal geometry and a Cev symmetry. (a) Assign x, y, z coordinates on the atoms: - Z axis on central Ta atom is the principal rotation axis (z axes on other atoms are colinear) - X, y axes on central Ta atom match Ta-H bonds (x, y axes on other atoms are...
Can you explain how to determine least count on question 5. DQuestion 5 12.5 pts Examine...
Can you explain how to determine least count on
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DQuestion 5 12.5 pts Examine the place value for the estimated digit and determine what must be the least count (i.e. the smallest increment) on the measuring device a. 12.30 cm Select b.72.9g0.1m c. 12.15 mL ISelect] d. 172.0oC- Select] 0.001 cm 0.01 cm Question 6 12.5 pts ina measurements indicate which one is the estimated digit and also indicate the
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Please explain how you do this. Thank you! 30. Determine what type of atomic orbitals were...
Please explain how you do this. Thank you!
30. Determine what type of atomic orbitals were used to form each of the bonds/lone pairs in the following molecules: (3 pts)
can you please explain how to determine which 2 ratios to select to test? also how...
can you please explain how to determine which 2 ratios to select
to test? also how do you determine the cross type from this info
when the question doesn't as, for the type of epistasis?
4. Use Chi-square to test which of 2 possible ratios is the most probable ratio of progeny kernels. Use this information to determine the cross type and parental genotype. Show your work here or on a separate sheet to receive full credit. Cross type does...
Describe how a spectrometer works. In particular describe the type of dispersive element you might use...
Describe how a spectrometer works. In particular describe the type of dispersive element you might use in a spectrometer that acquires spectra in the 400-700 nm range in as much detail as you can. How would you need to alter the dispersive element if you wanted to take the spectrum of an object at much shorter wavelengths (x-rays wavelengths; I = 5 nm) or longer wavelengths (mid-infrared wavelengths; 1 = 10 microns)?
java 4. Java allows for the use of generic typing to do away with all type...
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5) (A) What is the backbone of sphingolipids? (B) What type of linkage is found between...
5) (A) What is the backbone of sphingolipids? (B) What type of linkage is found between the sphinolipid backbone and a fatty acid? Is this the same type of linkage most commonly seen in other lipids? (C) What two types of linkages can be found between the sphingolipid backbone and the polar head group? (3 pts) 6) Describe primary and secondary active transport. How do these mechanisms vary from facilitate diffusion? (3 pts)
5. Professor Karl von Fildenshmirtzen is studying a transition metal ligand exchange reaction as follows below and is attempting to determine whether or not the mechanism is associative or dissociative (RDS rate-determining step): Dissociative X RDS + Associative L RDS X + a. Describe how Professor Fildenshmirtzen may distinguish between these two mechanisms using an Eyring plot. b. The AS for the reaction was determined to be negative. Which mechanism is operative?
Could you show how to do (d) step by step, please?
AO = Atomic orbital
MO = Molecular orbital
(L)GO= (Ligand) Group orbital
2. TaHs has a square pyramidal geometry and a Cev symmetry. (a) Assign x, y, z coordinates on the atoms: - Z axis on central Ta atom is the principal rotation axis (z axes on other atoms are colinear) - X, y axes on central Ta atom match Ta-H bonds (x, y axes on other atoms are...
Can you explain how to determine least count on
question 5.
DQuestion 5 12.5 pts Examine the place value for the estimated digit and determine what must be the least count (i.e. the smallest increment) on the measuring device a. 12.30 cm Select b.72.9g0.1m c. 12.15 mL ISelect] d. 172.0oC- Select] 0.001 cm 0.01 cm Question 6 12.5 pts ina measurements indicate which one is the estimated digit and also indicate the
Please explain how you do this. Thank you!
30. Determine what type of atomic orbitals were used to form each of the bonds/lone pairs in the following molecules: (3 pts)
can you please explain how to determine which 2 ratios to select
to test? also how do you determine the cross type from this info
when the question doesn't as, for the type of epistasis?
4. Use Chi-square to test which of 2 possible ratios is the most probable ratio of progeny kernels. Use this information to determine the cross type and parental genotype. Show your work here or on a separate sheet to receive full credit. Cross type does...
Describe how a spectrometer works. In particular describe the type of dispersive element you might use in a spectrometer that acquires spectra in the 400-700 nm range in as much detail as you can. How would you need to alter the dispersive element if you wanted to take the spectrum of an object at much shorter wavelengths (x-rays wavelengths; I = 5 nm) or longer wavelengths (mid-infrared wavelengths; 1 = 10 microns)?
5) (A) What is the backbone of sphingolipids? (B) What type of linkage is found between the sphinolipid backbone and a fatty acid? Is this the same type of linkage most commonly seen in other lipids? (C) What two types of linkages can be found between the sphingolipid backbone and the polar head group? (3 pts) 6) Describe primary and secondary active transport. How do these mechanisms vary from facilitate diffusion? (3 pts)
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