At time t = 0, the butadiene is introduced into an empty reactor at a temperature of 643K. the substance undergoes the following dimerization: 2?4?6 → ?8?12. Which was measured through the total pressure of the system, giving the following values as a function of time:
|
t/s |
P/Torr |
|
0 |
632 |
|
367 |
606.6 |
|
731 |
584.2 |
|
1038 |
567.3 |
|
1752 |
535.4 |
|
2550 |
509.3 |
|
3652 |
482.8 |
|
5403 |
453.3 |
|
7140 |
432.8 |
|
10600 |
405.3 |
Graph the data and get the order of reaction, as well as the value of the kinetic constant.
At time t = 0, the butadiene is introduced into an empty reactor at a temperature...