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Why is a standard KCl solution used to determine the cell constant, instead of the cell's...

Why is a standard KCl solution used to determine the cell constant, instead of the cell's dimensions? Is it more accurate? If so, why?

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Answer #1

Manual measurement of length and area of the electrode is pretty vague and you end up in error. The measurements are not that accurate. Hence we use standard KCl solution to calibrate the conductivity cell. This helps you to measure the resistance of known solution which will then helps you to find exactly the cell constant l/A where l= length and A is the area of the electrode.

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