The enthalpy of sublimation of a solid is always ______ than the enthalpy of fusion, and the enthalpy of vaporization of a liquid is always ______ than the enthalpy of fusion.
Greater, greater
Less, less
Less, greater
Greater, less
In sublimation, the molecules go directly from the solid phase to the gaseous phase. So, it requires greater energy than the energy required in fusion, as at any temperature the energy of gaseous phase is greater than the energy of the liquid phase.
A molecule requires greater amount of energy to go from liquid phase to gaseous phase because the energy of the gaseous phase is very high.
So, again, the enthalpy of vaporization of a liquid is always greater than the enthalpy of fusion.
So,
Greater, greater
Comment if any problem.
The enthalpy of sublimation of a solid is always ______ than the enthalpy of fusion, and...
13 The equations of the sublimation and the vaporization curves of a particular material are given by (sublimation). (vaporization) In P 0.04-6/T In P 0.03 - 4/T T + dT = const. T const. Figure 8.4 P. o diagrarn for an infinitesimal Carn ot cycle. where P is in atmospheres (a) Find the temperature of the triple point. (b) Show that the spe cific latent heats of vaporization and sublimation are 4R and 6R, respectively. (You may assume that the...
Ethanol melts at 159K and boils at 351K. The enthalpy of fusion is 5.02 kJ/mol, the enthalpy of vaporization is 35.56 kJ/mol, and the molar mass is 46.07 g/mol. The specific heats of solid ethanol is 0.97 J/g-K, for liquid ethanol it is 2.3 J/g-K, and for gaseous ethanol it is 1.9 J/g-K. How much heat (kJ) is needed to convert 215 g of liquid ethanol at 160 K to gaseous ethanol at 713 K?
2)) Find the heat of fusion (H°) for a substance whose heat of sublimation is 38 kJ/mol and heat of vaporization is 23 kJ/mol.
2)) Find the heat of fusion (H°) for a substance whose heat of sublimation is 38 kJ/mol and heat of vaporization is 23 kJ/mol.
The molar enthalpy of fusion of solid bismuth is 11.0 kJ mol-1, and the molar entropy of fusion is 20.2 J K-1 mol-1. (a) Calculate the Gibbs free energy change for the melting of 1.00 mol of bismuth at 575 K. kJ (b) Calculate the Gibbs free energy change for the conversion of 5.12 mol of solid bismuth to liquid bismuth at 575 K. kJ (c) Will bismuth melt spontaneously at 575 K? (d) At what temperature are solid and...
q 2 and 4 please!
Question 2 Which of the following compounds will hydrogen bond with water (H20)? Select all that apply. Cl2 CC14 CH20 NH3 SCI2 Question 3 Which of the following will have the lowest boiling point? Ne OKr O Ar o Не Question 4 Which of the following statements is FALSE? O A compound with stronger intermolecular forces will have a higher boiling point When a substance melts, some - but not all- of the intermolecular forces...
Ethanol (C2H5OH) melts at -114 ∘C and boils at 78 ∘C. The enthalpy of fusion of ethanol is 5.02 kJ/mol, and its enthalpy of vaporization is 38.56 kJ/mol. The specific heat of solid and liquid ethanol are 0.97 J/g⋅K are 2.3 J/g⋅K respectively. How much heat is required to convert 32.0 g of ethanol at -161 ∘C to the vapor phase at 78 ∘C? Express your answer using two significant figures.
Ethanol (C2H5OH) melts at -114 ∘C and boils at 78 ∘C. The enthalpy of fusion of ethanol is 5.02 kJ/mol, and its enthalpy of vaporization is 38.56 kJ/mol. The specific heat of solid and liquid ethanol are 0.97 J/g⋅K are 2.3 J/g⋅K respectively. A) How much heat is required to convert 30.5 g of ethanol at 30 ∘C to the vapor phase at 78 ∘C? Q=______kJ B)How much heat is required to convert 30.5 g of ethanol at -167 ∘C...
1. The normal boiling point of benzene (i.e., at 1 atm) is 80.09 °C. The molar enthalpy of vaporization is 30.72 kJ mol . Assuming that AvapHm and AvapSm stay constant at their values at 80.09°C, calculate the values of AvapGm at 75.0 °C, 80.09 °C and 85.0 °C. Given your calculated values, do you still expect benzene to spontaneously condense at 75.0 °C and to spontaneously evaporate at 85.0°C? -1 2. The vapor pressure of a liquid was measured...
The enthalpy of fusion of cadmium at its normal melting point of 321 °C is 6.11 kJ mol? What is the entropy of fusion of cadmium at this temperature? ASfus = J mol-K-1 The molar enthalpy of fusion of solid cadmium is 6.11 kJ mol-1, and the molar entropy of fusion is 10.3 JK+mol-1. (a) Calculate the Gibbs free energy change for the melting of 1.00 mol of cadmium at 622 K. (b) Calculate the Gibbs free energy change for...
1. Table I gives the vapor pressure of tetrachloromethand Table 1: Data for Problem at various temperatures for the solid and liquid phases. Phase Assuming ideal gas behavior, calculate: Solid i 230.0 K A. the change in the molar enthalpy of sublimation Solid F. 250.0K (HINT: use value for the "starting" phase) Liquid in 280.0 K B. the change in the molar enthalpy of vaporization (HINT: use value for the "starting" phase) Liquid final 340.0 K C. the change in...