Question

For a 1.0 M solution of H2S at equilibrium, which of the following statements are correct?...

For a 1.0 M solution of H2S at equilibrium, which of the following statements are correct? Ka: H2S = 9.1 x 10-8 HS- = 1.0 x 10-13 1. [H3O+] = [H2S] 2. [OH-] = 1.0 x 10-7 M 3. [HS-] = 9.1 x 10-8 M 4. [S2-] = 1.0 x 10-13 M

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Answer #1

The correct statement is : (4.) [S2-] = 1.0 x 10-13 M

Explanation

Aqueous H2S is weak acid. H2S does not dissociate completely which means hydronium ion concentration, [H3O+] cannot be equal to H2S concentration because only a small part of H2S is converted to H3O+

Since the solution is weakly acidic, therefore [H3O+] > 1.0 x 10-7 M. This means [OH-] < 1.0 x 10-7 M

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