Which mechanism is consistent with the rate law rate = k[A][B]for the reaction A + 2B --> 2C?
A) Step 1. A + B ---> F, slow
Step 2. B + F ---> 2C, fast
B) Step 1. B + B ---> D, slow
Step 2. A + D ---> 2C, fast
C) Step 1. A + A ---> E, slow
Step 2. B + E ---> 2C, fast
D) Step 1. A + B ---> G, fast
Step 2. B + G ---> 2C, slow
E) Step 1. A + 2B ---> 2C
Which mechanism is consistent with the rate law rate = k[A][B]for the reaction A + 2B...
A possible mechanism for the next decomposition reaction is A(g) 2B(g)C (fast equilibrium) 2C +A(g) 2B(g) (slow) What is a rate law that is consistent with this mechanism? Select one: k A B2 k [A]3[B] O a. Rate b. Rate O c. Rate k [A)MB2 O d. Rate k [A3[B2 O f. Rate -k [A/TE] O g. Rate k [A3/[B) h. Rate k [A]3[B]4
Consider the overall reaction.... A+B--C+D which has an observed rate law of Rate=k[A12 Which of the following choices would be a sensible 2-step mechanism, given this observed rate law? O A+A-->E slow E+B-->C+D fast A+B--> 2 E --> C+D fast slow A+A-->E E+B-->C+D fast slow A+B-->E 2 E -->C+D slow fast
4. For the reaction A+B → C+D we find that the rate law is v=k[A]”[B]° Which of the following mechanisms is consistent with the rate law? Explain in detail. a) A+B → C+D b) A+A ~ A2 (fast step) A2 +B → C+D (slow step) c) A+A → A2 (slow step) A2+B → C+D (fast step) d) A+A → A2 (fast equilibrium) A2+B → C+D (slow step)
16. For the overall reaction which of the following mechanisms is consistent with the rate equation below? rate = k[A] [B]2 a. 2A + B →I (fast) I + B → C + A (slow) A + B → 1 (slow) 1 + B → C (fast) 2B → 1 (slow) A + 1 → C (fast) 2B→1(fast) 1 + A → C (slow) A + 2B → 1 (fast) 1 + B → C + B (slow) b, d....
e . b. (- R 0.3 14 J/ k -mol) 6.4×10-4 M.'si c. 2.1 x 103 M's d. 3.6×10-3 Migl e. 2.5x 1026M''s 23. Nitrogen dioxide reacts with carbon monoxide to produce nitrogen monoxide NO2(g) + CO(g) → NO(g) + CO2(g) A proposed mechanism for this reaction is 2 NO2(g) → NO2(g) + NO(g) (fast, equilibrium) N03(g) + CO(g) → NO2(g) + CO2(g) (slow) What is a rate law that is consistent with the proposed mechanism? a. rate = k[NO2][CO]...
5. Which mechanism would be appropriate for a reaction that had the rate law: Rate =k[A]?? A) A+B=C fast B) A+AD slow C) A+B=C fast A+A=D slow D+B=C fast A+B=C slow D) A+B=C fast A+C=D slow
For the reaction A + 2B → C + D, the rate law is found to be rate = k[A][B]. The following mechanism, is proposed to explain the reaction. l+B→C+D a) Show that the proposed mechanism is consistent with the stoichiometry of the reaction. b) Which step must be the rate determining step? c) What is "T" called? Ca ta y st
A mechanism for the gas phase reaction of fluorine with chlorine dioxide that is consistent with the observed rate law is: step slow: F2+CIO, FCIO, + F step 2 fast: F+CIO, FCIO, (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. (2) Which species acts as a catalyst? Enter formula. If none, leave box blank (3) Which species acts as a reaction intermediate? Enter formula....
A mechanism for the gas phase reaction of fluorine with chlorine dioxide that is consistent with the observed rate law is: step 1 slow: Fz+CIO, step 2 fast: F+CIO, FCIO, +F FCIO, (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. (2) Which species acts as a catalyst? Enter formula. If none, leave box blank: (3) Which species acts as a reaction intermediate? Enter formula....
The rate law for the reaction 2NO2 + O3 → N2O5 + O2 is rate = k[NO2][O3]. Which one of the following mechanisms is consistent with this rate law? A) NO2 + NO2 → N2O4 (fast) N2O4 + O3 → N2O5 + O2 (slow) B) NO2 + O3 → NO5 (fast) NO5 + NO5 → N2O5 + 5/2O2 (slow) C) NO2 + O3 → NO3 + O2 (slow) NO3 + NO2 → N2O5 (fast) D) NO2 + NO2 → N2O2...