Question

2K2Cr2O7 + 8H2SO4 + 3C2H5OH = 2Cr2(SO4)3 + 2K2SO4 + 3CH3COOH + 11H2O A=ebc A=absorbance e=molar...

2K2Cr2O7 + 8H2SO4 + 3C2H5OH = 2Cr2(SO4)3 + 2K2SO4 + 3CH3COOH + 11H2O

A=ebc

A=absorbance

e=molar absorptivity

b=path length of light through the cell

c=concentration of solution in moles per liter

A1/A2=C1/C2

A1= absorbance of known solution

c1=concentration of known solution

A2=absorbance of unknown solution

C2=concentration of unknown.

0.25MG ethanol = 0.10%BAC

Operating wavelength : 441 nm
Absorbance of solution 1 - Standard Dichromate-H2O : 0.533 a.u.
Absorbance of solution 2 - Standard Dichromate-Ethanol (Standard) : 0.422 a.u.
Absorbance of solution 3 - Standard Dichromate-Ethanol (Defendant) : 0.365 a.u.
Mass of dichromate in Solution 1 : 6.25 mg

II. Calculated data:

Enter the following calculated data from the calibration of the Breath-Analyzer:

Mass of dichromate in Solution 2 : mg

Mass of dichromate consumed : mg.

Number of moles of dichromate consumed : mmoles

Number of moles of ethanol consumed : mmoles

Mass of ethanol consumed : mg

%BAC of sample :

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