consider this six metal ligand , answer the following question. [Ni(NH3)6]Cl2,[Ni(en)3]Cl2.2H2O,[Ni(pn)3]Cl2.2H2O,[Ni(bipy)3]Cl2 and [Ni(phen)3]Cl2 1. Draw the...
consider this six metal ligand , answer the following question.
[Ni(NH3)6]Cl2,[Ni(en)3]Cl2.2H2O,[Ni(pn)3]Cl2.2H2O,[Ni(bipy)3]Cl2 and [Ni(phen)3]Cl2
1. Draw the structures of all of the ligands used in this experiment and place them in order of their increasing ligand field strengths. How does this compare with the spectrochemical series for ligands detailed in the literature?
2. Draw structures by hand (using 3D depictions for the metal-ligand bonds) for all of the metal complexes indicating which ones are chiral and which ones are not.
3. Choose one of the chiral compounds and draw both enantiomers by hand. Indicate the handedness of each (D or L).
Homework Answers
The solution and explanation of part 1 is given in the following two images
The part 2 solution is given below
The part 3 is explained in the following image
Add Answer to:
consider this six metal ligand , answer the following
question.
[Ni(NH3)6]Cl2,[Ni(en)3]Cl2.2H2O,[Ni(pn)3]Cl2.2H2O,[Ni(bipy)3]Cl2
and [Ni(phen)3]Cl2
1. Draw the...
SYNTHESIS OF TRANSITION METAL COORDINATION COM 3. Ethylenediamine ("en" in short-hand notation) has two amine group...
SYNTHESIS OF TRANSITION METAL COORDINATION COM 3. Ethylenediamine ("en" in short-hand notation) has two amine groups, one at each end of a two-carbon chain, NH,CH,CH,NH. Each nitrogen in NH,CH,CH_NH, has a lone pair that coordinates to the metal. Thus, one NH CH CH NH, ligand, takes up two coordina- tion sites. a) Draw and label the structures of the cis and trans isomers of Co(en),C1,CI. b) What is the coordination number for (Coſen),C1,CI? c) Determine the oxidation state of the...
SYNTHESIS OF TRANSITION METAL COORDINATION COM 3. Ethylenediamine ("en" in short-hand notation) has two amine groups, one at each end of a two-carbon chain, NH,CH,CH,NH. Each nitrogen in NH,CH,CH_NH, has a lone pair that coordinates to the metal. Thus, one NH CH CH NH, ligand, takes up two coordina- tion sites. a) Draw and label the structures of the cis and trans isomers of Co(en),C1,CI. b) What is the coordination number for (Coſen),C1,CI? c) Determine the oxidation state of the...
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