For the gas phase decomposition of trichloromethyl chloroformate, ClCOOCCl32 COCl2 the rate constant has been determined...
For the gas phase decomposition of trichloromethyl chloroformate, ClCOOCCl32 COCl2 the rate constant has been determined at several temperatures. When ln k in s-1 is plotted against the reciprocal of the Kelvin temperature, the resulting linear plot has a slope of -2.09×104 K and a y-intercept of 30.3. The activation energy for the gas phase decomposition of trichloromethyl chloroformate is __________kJ/mol.
Homework Answers
According to the Arrhenius equaton
When ln k is plotted vs 1/T, the slope 
......(2)
The slope 
......(1)
From equations (1) and (2)
Convert unit from J/mol to kJ/mol
Hence, the activation energy for the gas phase decomposition of
trichloromethyl chloroformate is 
.
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For the gas phase decomposition of trichloromethyl
chloroformate, ClCOOCCl32 COCl2 the rate constant has been
determined...
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