Hello! How can I lower the energy of the cis geomrety to an energy lower than...

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Hello! How can I lower the energy of the cis geomrety to an energy lower than...

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How can I lower the energy of the cis geomrety to an energy lower than trans? I'm working with 1,3 butadiene. Ive tried adding substituents to the cis and the energy was lowered but not lower than the trans species.

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