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Arrange the following solutions in order of increasing freezing point depression: A. 0.10 m MgCl2 in...

Arrange the following solutions in order of increasing freezing point depression:

A. 0.10 m MgCl2 in water, i = 2.7, Kf = 1.86°C/m
B. 0.16 m toluene in diethyl ether, i = 1.00, Kf = 1.79°C/m
C. 0.24 m ethylene glycol in ethanol, i = 1.00, Kf = 1.99°C/m

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Answer #1

The freezing point depression constant is the degrees that the freezing point of the solvent is lowered when 1 mole of a solute is dissolved in 1 kg grams of the solvent.

When a solute is dissolved in a solvent, the freezing point of the solvent is lowered.

Depression in freezing point = i*Kf*m

where, Kf = cryoscopic constant for the solvent
m = molality.. moles solute / kg solvent
i = van't hoff factor = ions 1 molecule of solute dissociates into in solution.
so order is B<C<A

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