Question

Find the order of the reaction for the dye and the units for k'. I am...

Find the order of the reaction for the dye and the units for k'.

I am not sure what data is needed so I just paste them all, hope it helps, thank you!

Rate = k[dye]m[OCl-]n
Rate = k'[dye]m where k' = k[OCl-]n

Molar concentration of the dye stock solution: 2.52e-5 mol/L

Operating Wavelength: 631 nm

Solutions Volume(mL) of Blue#1 stock solution Volume(mL) of distilled H20 Absorbance (A)
(a.u.)
1

1.00

19.00 0.052
2 2.00 18.00 0.121
3 4.00 16.00 0.213
4 8.00 12.00 0.537

[dye] = 1.96×10-5x A

Solutions
(Dilutions)
OCl- Concentration
mol/L
Experiment 1 0.034
Experiment 2 0.067
Experiment 3

0.13

Experiment 1
Time
(s)
Absorbance
(a.u.)
[dye]
(mol/L) x 10-6
15 0.980 19.2
30 0.941 18.4
45 0.909 17.8
75 0.849 16.6
90 0.808 15.8
105 0.781 15.3
120 0.750 14.7
135 0.721 14.1
150 0.690 13.5
165 0.660 12.9
Experiment 2
Time
(s)
Absorbance
(a.u.)
[dye]
(mol/L) x 10-6
15 0.863 16.9
30 0.789 15.4
45 0.720 14.1
60 0.652 12.8
75 0.592 11.6
90 0.538 10.5
105 0.486 9.51
120 0.441 8.63
135 0.397 7.77
150 0.358 7.01
Experiment 3
Time
(s)
Absorbance
(a.u.)
[dye]
(mol/L) x 10-6
10 0.747 14.6
20 0.649 12.7
30 0.563 11.0
40 0.486 9.51
50 0.418 8.18
60 0.361 7.06
70 0.310 6.07
80 0.267 5.22
90 0.228 4.46
100 0.197 3.85
0 0
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Answer #1

The order of above reaction is 2 i.e. reaction a second order and the unites of K for second order reaction are

where M is mole and s in seconds.

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