Question

1) Which combination is the best choice to use when preparing a buffer with a pH...

1) Which combination is the best choice to use when preparing a buffer with a pH of 5.5?
A) HNO2; NaNO2 (pKa for HNO2 = 3.33)

B) HCHO2; NaCHO2 (pKa for HCHO2 = 3.74)

C) C5H5N; C5H5NHCl (pKb for C5H5N = 8.76)

D) NH3; NH4Cl (pKb for NH3 = 4.75)

2) A 100 mL solution of 0.500 M hydrocyanic acid is titrated with a 0.125 M solution of potassium hydroxide. What is the pH of the solution after the addition of 500 mL of the potassium hydroxide solution?  
- For hydrocyanic acid: Ka = 4.9 x 10-10 and pKa = 9.31
- report answer in three significant figures

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