Give products for the following questions.
(for the last question marked as *, show the stereochemistry and regiochemistry)

Give products for the following questions. (for the last question marked as *, show the stereoche...
39. actions and give the structures of any intermediates. 1. Complete the major products of the following reactions and give Include stereochemistry, when appropriate. 1) BH, THE 2)H,0OH Bra но KMnO, OH theat) Oso4 H202 110, 2) (CH3) 21 HGCOAC), H0 1) Hg(OAc) H2O c) H20 H2SO4 2) NaBHA H2 1)03 2) (CH3)2s Pd-C CH3OH
give the major organic products for the following reactions or
sequence of reactions. show all relevant stereo chemistry.
Give the major organic product(s) for the following reactions or sequence of reactions. Show all relevant stereochemistry HC но" 1. HC L 1. CH,MgBr, ether 2. 1,0
8. Predict the products of the following reactions. Show the proper regiochemistry and/or stereochemistry where appropriate. SCOAda/H20 (1) 03 (-78%) HELAN (2) (CH3)25 CH₂ I2, Zn (ca) nor H2O (1) MCPBA (2) H300 HBC trans ROOR > Malkenes Osoy Hal H2O2 (1) BH3. THE pt Hol Cothre) Biz cay (solvent)
Give the products for the following oxidation-reduction
reaction. Show stereochemistry when applicable.
Give the products for the following oxidation-reduction
reactions as well please
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Give the syn or anti addition products for the following addition reactions. Show appropriate stereochemistry if necessary to get the full credits. (5 points total) H2/Pt 1 point Br2 1 point 1. BH3 2. H2O2/KOH 1.5 points D Br2/H2O Brytzo 1.5 points
Give the organic products, with the CORRECT REGIOCHEMISTRY AND
STEREOCHEMISTRY, when appropriate. !!!
CH3 -C CH-CH + HI Нас CH2OOCH C CH-CH2CH3 +HBr Pd + D2 CH3 Но C CH- CH2CH3 Н-о + Нас 1) (BH3)2, THF 2) H-0,. ОН" Cн, Н.о" CH3CO;H CH3 CHCI/ KOH cCH Hас H +Cl2
2. Give the syn or anti addition products for the following addition reactions. Show appropriate stereochemistry if necessary to get the full credits. (5 points total) H2/Pt D Help! 1 point Brz 1 point 1. BH3 2. H2O2/KOH 1.5 points y Broltzo Brz/H20 1.5 points
2. Give the syn or anti addition products for the following addition reactions. Show appropriate stereochemistry if necessary to get the full credits. (5 points total) H2/Pt D HPA 1 point 1 point 1. BH3 2. H2O2/KOH 1.5 points o Brutto Br2/H20 1.5 points
Give products. Be sure to show stereochemistry where
appropriate
The net result is anti addition - the two Br add to opposite faces of the Cl_2 can also be used; F_2 is too reactive, I_2 not reactive enough. Give products. Be sure to show stereochemistry where appropriate. Other species such as water can act as nucleophile; e.g. Halohydrin formation can be thought of as following Markovnikov Br^+ and OH^- instead of H and X
2. (12 pts) Reactions Give the reagents or products to the following systems. If a reaction does not give a product, write "NR" for No Reaction. Provide the product with the highest yield. Assume 1 to 1 stoichiometry unless otherwise stated. Provide stereochemistry if applicable. NC heat но но H ETOH 1. SOCI2 2. Heat, Hас -о н Но H но ETOH 1. TsCl NC H но но Н 2. CH,ок, CH,он