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Calculate the lattice energy for PbS using electrostatic forces (assume that it is in a Rock Salt type lattice, although you should be able to determine this). Make sure you use the Born-Mayer correc...

  1. Calculate the lattice energy for PbS using electrostatic forces (assume that it is in a Rock Salt type lattice, although you should be able to determine this). Make sure you use the Born-Mayer correction. Compare the results with the Born-Haber cycle values that you calculate. (All necessary energy values can either be found in your text, at www.webelements.com, or from the following: the 2nd EA of S = 640 kJ/mol (it should be noted that the 1st EA of S in this table was listed as a negative value) the ΔHfº of PbS is -98.3 kJ/mol.  
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