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Consider the species Cl2+, Cl2,and Cl2−. Which of these species willbe paramagnetic? a. Only Cl2 b. Cl...

Consider the species Cl2+, Cl2,and Cl2. Which of these species willbe paramagnetic?
a. Only Cl2 b. Cl2+ and Cl2 c. Cl2 andCl2 d. Cl2+ andCl2 e. All three areparamagnetic.
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Answer #1
Cl2 molecule is formed when the atomicorbitals of 2 Cl atoms are linearly combined . Each Cl is having 17electrons and in the valency shell 7 electrons are present .Leaving the inner shell , we can have 14 electrons in the valencyshell of the molecule .
In Cl2 molecule as all electronsare paired up .So it is diamagnetic in nature.
Cl2+ is formed when anelectron is removed from the valency shell of the molecule .So now we can have 1 unpaired electron in the valency shell of themolecule . So it is paramagnetic in nature .
Cl2 is formed when anelectron is added to the valency shell of the molecule . Sonow we can have 1 unpaired electron in the valency shell of themolecule . So it is also paramagnetic in nature .
∴ Cl2+ andCl2 are paramagnetic in nature.
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