The concepts used to solve this problem is the synthesis of enolate ion from ketone under basic conditions. The enolate ions are resonance stabilized. It has two forms, namely carbanion, and an oxyanion.
Show the formation of carbanion and oxyanion by removing each different .
Enolate ion:
It is an ion which is formed by removing from aldehyde and ketone. It can be formed both in acidic and basic condition.
The mechanism of the synthesis of enolate is shown below.
The mechanism of the synthesis of enolate is shown below.
The oxyanions formed from the ketone under basic condition are as follows.
Draw both enolates formed when the ketone is treated with base. Include charges. Draw the oxyanion species; do not dra...
Draw both enolates formed when the ketone is treated with base. Include charges. Draw the oxyanion species; do not draw carbanion resonance forms.
Draw both enolates formed when the ketone is treated with base. Include charges. Draw the oxyanion species; do not draw carbanion resonance forms. iv → Hint Previous Give Up & View Solution Check Answer Next Exit about us Careers privacy policy terms of use contact us help MacBook Pro
Draw the kinetic and thermodynamic enolates formed when 3-methylbutan-2-one (methyl isopropyl ketone) is treated with base. Include charges. Draw the oxyanion species; do not draw carbanion resonance forms.
Draw the kinetic and thermodynamic enolates formed when 3-methylbutan-2-one (methyl isopropyl ketone) is treated with base. Include charges. Draw the oxyanion species;do not draw carbanion resonance forms.
Ketones are converted to enolates on treatment with base. Draw the structures of the carbanion enolate formed when the ketone shown is treated with either LDA or tert-butoxide Include all lone pairs of electrons and nonzero formal charges. Do not include counter ions. Have you considered the difference between the two bases used? Have you remembered to include all lone pairs of electrons and nonzero charges your enolate structures? Are you certain about which carbon (s) in the ketone get...
Draw both resonance structures of the enolate formed when each of the following ketones is treated with a strong base. Show mechanisms.
Draw both resonance structures of the product formed when the following starting material is treated with LDA in THF solution at -78°C. draw structure ... draw structure ... (Negative charge on carbon) (Negative charge on nitrogen)
Draw the alkyne formed when 2,3-dichloropentane is treated with
an excess of strong base such as sodium amide.
Draw the alkyne formed when 2,3-dichloropentane is treated with an excess of strong base such as sodium amide.
Draw the enolate ion that is formed when the following molecule is treated with NaOH. Draw the resonance structures of the enolate. Draw the products formed in the following reactions
Draw the alkyne formed when 3,4-dichloroheptane is treated with
an excess of strong base such as sodium amide.