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Practice Set-III NAHCO3, 200°C CeHeO4 CO2C2HS 7 NaOC2Hs, heat C12H1203 HCO2C2HS 1) LiN[Si(CH3)3lz 2) H30* C1SH2203 CO2C...
Predict the structure of the products of the following reactions C2H9O2C CH2 1) NaOC2Hs C19H18O3 1 CaHs CHs 2) H30...
Predict the structure of the products of the following reactions C2H9O2C CH2 1) NaOC2Hs C19H18O3 1 CaHs CHs 2) H30 & heat C2HtsO2c C2H502C. 1) NaOC2Hs & heat CH2 2 co2CaHs 2) H30 & heat C7H1003 2 C2H502C 1) NaOC2Hs & heat C13H1805 .CO2C2Hs 2 +CH2-O 3 2) H30, 0 °C 1) NaOC2Hs & heat CO2C2H5 2 C7H4O6 4 2) H30 CO2C2HS C19H21NO +2 CEH5CHONH4OAC C2Hg02C 1) aq. NaHCO3 2) Ha0 & heat c o CaHgO2C- C12H1602 +2
Predict the...
Practice Set-Il1 Claisen Product of the following easters: 2. co2C2Hs CH3 3. 02C2Hs Predict the structure of the produc...
Practice Set-Il1 Claisen Product of the following easters: 2. co2C2Hs CH3 3. 02C2Hs Predict the structure of the products of the following reactions C2H501)NaOC2s 1 C6H5 1) NaOCHs& heat 22)H30 a heat H1003 2 0 Co2C2Hs CH2-O 3 2 2 Co:CHs1) NaoCHts & heat +2 2) H3O & heat
Practice Set-Il1 Claisen Product of the following easters: 2. co2C2Hs CH3 3. 02C2Hs Predict the structure of the products of the following reactions C2H501)NaOC2s 1 C6H5 1) NaOCHs& heat 22)H30 a...
Practice Set-lll SET-II 1) C.HNH 1. 2) LIAIH, in ether ? 3) H2O) 1) NaOC Hs ; then CeHsCH CH-Br 2. HCO2C2H5 2) H20...
Practice Set-lll SET-II 1) C.HNH 1. 2) LIAIH, in ether ? 3) H2O) 1) NaOC Hs ; then CeHsCH CH-Br 2. HCO2C2H5 2) H20 ? & heat H CO2C2H5 3) SOcl, ; then AICI3 & heat 1) Mg in ether 3. ? CHa-CI 2) (CH) CH-CN H2C 3) H3O CH3 1) NaOC,Hs; then CHs-I 2) H3O& heat 4. ? O-CaHs )CHCHO & NaOH; heat SET-III Stage Two Stage Three Stage One
Practice Set-lll SET-II 1) C.HNH 1. 2) LIAIH, in...
colecta NaOH H + CH3 then heat NaOH tir then heat NaOH (CH3)2Culi then heat 1....
colecta NaOH H + CH3 then heat NaOH tir then heat NaOH (CH3)2Culi then heat 1. NaOCH3 CH3OH OCH3 2. dil. HCI O 1. LDA 1. LIAIHA het hy 2. Br 2. H2O* 1. NaOCH3 1. NaOCH3 2. CI OCH; 2. Ph Br 3. H3O+, heat 1. LDA 1. LDA 요 2. 0 CI 3. H3O+ 2. H 3. H30+
OH 1. NaOCHZ 2. H20 CO2H acid catalyst hint: - BuOH 1 2 NaOH, H2O heat...
OH 1. NaOCHZ 2. H20 CO2H acid catalyst hint: - BuOH 1 2 NaOH, H2O heat 1. (CH3)2CuLi, ether 2. H30* H 3 1. NaOCH3 u 1. H307 2. heat 2. Br Br 5 6
li NaOH, H20 heat 1. (CH3)2Culi, ether 2. H30* H 3 4
li NaOH, H20 heat 1. (CH3)2Culi, ether 2. H30* H 3 4
C₂H₂O (1) Na show (h) Stereochem (2) H,0* (1) P (OM), heat ..- C₂2H1 202 show...
C₂H₂O (1) Na show (h) Stereochem (2) H,0* (1) P (OM), heat ..- C₂2H1 202 show stereochem (2) Buli (3) W cils HC- 0- N CH3 CH + CHC1, show stereochem CH, H.C+01 CH heat (1) H, MgBr Phi (2) H30 (3) PCC
Carboxylic acid problems 1) KMnO4, NaOH 1) KMnO4. NaOH Heat 2) H30 Cr Heat 2) H2O*cr...
Carboxylic acid problems 1) KMnO4, NaOH 1) KMnO4. NaOH Heat 2) H30 Cr Heat 2) H2O*cr 1) Ag20 or Ag(NH3)2*OH 1) Og 2) H,02 H2) H30°C KMnO4 CH3(CH2)6CH2 CH2(CH2)CH2COH C=C HH H30+ Oleic acid HO 1) KMnO4, NaOH Heat 2) H30*cr CH3 CH3CHCH2CH2CH2OH 4-Methyl-1-pentanol H30+ OH 1) H.CO. CH3CH2CH2CH2CH2CH Hexanal CHE 212 CH 15 & 16 Cathexaulic Acids. 22
Practice Set-lll CH3 o 1. H3c-C- CHa a HaC, CH3 PY ? H-C-N H Нас + OH T CH2 2. ? CH2 he N(CH3)2 O2N HaC CH3 Phosgen...
Practice Set-lll CH3 o 1. H3c-C- CHa a HaC, CH3 PY ? H-C-N H Нас + OH T CH2 2. ? CH2 he N(CH3)2 O2N HaC CH3 Phosgene, ? (Review a 3. O-CC2 2 CO2H PY ? HaC 4. Нас OH +CH3 NH2 ? H + excess CH30H ? 6. CH(CH2)16 heat b-(CH2)1CH3 heat ? 7. CaHs-C O-CH2 + NH2-OH hydrorylarnine O-
Practice Set-lll CH3 o 1. H3c-C- CHa a HaC, CH3 PY ? H-C-N H Нас + OH T...
2. Predict the product. CH,CHINH Or . 1. excess CH 1 2. Ag,0,H,O heat 5. Match...
2. Predict the product. CH,CHINH Or . 1. excess CH 1 2. Ag,0,H,O heat 5. Match the reagents to the corresponding reaction. G. H20 H. xs CH3CH2NH2 A. SOCI2, pyridine B. Ethanol, pyridine C. 1) xs LAH 2) H20 D. 1) xs CH,CHMgBr 2) H30 E. 1) NaOH 2) H30* F. 1) DIBAH 2) H20 1. 1) LiAl(OR)2) H20 J. (CH2CH2) Culi K. xs NH3 L. 1) NaOH 2) CHÚCHỊCHÚCOCI M. Butanol, H
Predict the structure of the products of the following reactions C2H9O2C CH2 1) NaOC2Hs C19H18O3 1 CaHs CHs 2) H30 & heat C2HtsO2c C2H502C. 1) NaOC2Hs & heat CH2 2 co2CaHs 2) H30 & heat C7H1003 2 C2H502C 1) NaOC2Hs & heat C13H1805 .CO2C2Hs 2 +CH2-O 3 2) H30, 0 °C 1) NaOC2Hs & heat CO2C2H5 2 C7H4O6 4 2) H30 CO2C2HS C19H21NO +2 CEH5CHONH4OAC C2Hg02C 1) aq. NaHCO3 2) Ha0 & heat c o CaHgO2C- C12H1602 +2
Predict the...
Practice Set-Il1 Claisen Product of the following easters: 2. co2C2Hs CH3 3. 02C2Hs Predict the structure of the products of the following reactions C2H501)NaOC2s 1 C6H5 1) NaOCHs& heat 22)H30 a heat H1003 2 0 Co2C2Hs CH2-O 3 2 2 Co:CHs1) NaoCHts & heat +2 2) H3O & heat
Practice Set-Il1 Claisen Product of the following easters: 2. co2C2Hs CH3 3. 02C2Hs Predict the structure of the products of the following reactions C2H501)NaOC2s 1 C6H5 1) NaOCHs& heat 22)H30 a...
Practice Set-lll SET-II 1) C.HNH 1. 2) LIAIH, in ether ? 3) H2O) 1) NaOC Hs ; then CeHsCH CH-Br 2. HCO2C2H5 2) H20 ? & heat H CO2C2H5 3) SOcl, ; then AICI3 & heat 1) Mg in ether 3. ? CHa-CI 2) (CH) CH-CN H2C 3) H3O CH3 1) NaOC,Hs; then CHs-I 2) H3O& heat 4. ? O-CaHs )CHCHO & NaOH; heat SET-III Stage Two Stage Three Stage One
Practice Set-lll SET-II 1) C.HNH 1. 2) LIAIH, in...
colecta NaOH H + CH3 then heat NaOH tir then heat NaOH (CH3)2Culi then heat 1. NaOCH3 CH3OH OCH3 2. dil. HCI O 1. LDA 1. LIAIHA het hy 2. Br 2. H2O* 1. NaOCH3 1. NaOCH3 2. CI OCH; 2. Ph Br 3. H3O+, heat 1. LDA 1. LDA 요 2. 0 CI 3. H3O+ 2. H 3. H30+
OH 1. NaOCHZ 2. H20 CO2H acid catalyst hint: - BuOH 1 2 NaOH, H2O heat 1. (CH3)2CuLi, ether 2. H30* H 3 1. NaOCH3 u 1. H307 2. heat 2. Br Br 5 6
li NaOH, H20 heat 1. (CH3)2Culi, ether 2. H30* H 3 4
C₂H₂O (1) Na show (h) Stereochem (2) H,0* (1) P (OM), heat ..- C₂2H1 202 show stereochem (2) Buli (3) W cils HC- 0- N CH3 CH + CHC1, show stereochem CH, H.C+01 CH heat (1) H, MgBr Phi (2) H30 (3) PCC
Carboxylic acid problems 1) KMnO4, NaOH 1) KMnO4. NaOH Heat 2) H30 Cr Heat 2) H2O*cr 1) Ag20 or Ag(NH3)2*OH 1) Og 2) H,02 H2) H30°C KMnO4 CH3(CH2)6CH2 CH2(CH2)CH2COH C=C HH H30+ Oleic acid HO 1) KMnO4, NaOH Heat 2) H30*cr CH3 CH3CHCH2CH2CH2OH 4-Methyl-1-pentanol H30+ OH 1) H.CO. CH3CH2CH2CH2CH2CH Hexanal CHE 212 CH 15 & 16 Cathexaulic Acids. 22
Practice Set-lll CH3 o 1. H3c-C- CHa a HaC, CH3 PY ? H-C-N H Нас + OH T CH2 2. ? CH2 he N(CH3)2 O2N HaC CH3 Phosgene, ? (Review a 3. O-CC2 2 CO2H PY ? HaC 4. Нас OH +CH3 NH2 ? H + excess CH30H ? 6. CH(CH2)16 heat b-(CH2)1CH3 heat ? 7. CaHs-C O-CH2 + NH2-OH hydrorylarnine O-
Practice Set-lll CH3 o 1. H3c-C- CHa a HaC, CH3 PY ? H-C-N H Нас + OH T...
2. Predict the product. CH,CHINH Or . 1. excess CH 1 2. Ag,0,H,O heat 5. Match the reagents to the corresponding reaction. G. H20 H. xs CH3CH2NH2 A. SOCI2, pyridine B. Ethanol, pyridine C. 1) xs LAH 2) H20 D. 1) xs CH,CHMgBr 2) H30 E. 1) NaOH 2) H30* F. 1) DIBAH 2) H20 1. 1) LiAl(OR)2) H20 J. (CH2CH2) Culi K. xs NH3 L. 1) NaOH 2) CHÚCHỊCHÚCOCI M. Butanol, H
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