Reaction at cathode :
2H2O(l) + 2e-
H2(g) + 2 OH-(aq)
PV = nRT
n =1.0atm × 140.0L /(0.0821atm-L/K.mol × 273K)
= 6.2463 mol
2 mole of electrons or 2 Faradays are needed to release 1 mole of H2 gas.
Number of faraday passed to produce 6.2463mol of hydrogen = 2 × 6.2463 = 12.4926 faraday
Q = I×t
Time required to produce the desired hydrogen = 12.4926 × 96485 / 0.2300 = 5240638.371 second
= 5240638.371/(3600×24)
= 60.66days (answer)
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