Using Appendix D in the textbook, calculate the molar solubility of AgBr in 3.1×10−2 M AgNO3 solution.
Silver bromide AgBr 5.0 * 10-13
AgNO3 here is Strong electrolyte
It will dissociate completely to give [Ag+] = 0.031 M
At equilibrium:
AgBr <----> Ag+ + Br-
3.1*10^-2 +s s
Ksp = [Ag+][Br-]
5*10^-13=(3.1*10^-2 + s)*(s)
Since Ksp is small, s can be ignored as compared to 3.1*10^-2
Above expression thus becomes:
5*10^-13=(3.1*10^-2)*(s)
5*10^-13= 3.1*10^-2 * 1(s)^1
s = 1.613*10^-11 M
Answer: 1.6*10^-11 M
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