can someone show me how to do the work and explain it to meOPTION B
IN SN2 reactions , the tetrahdral carbon of the substrate is attacked by the nucleophile from backside.
The transition state thus contains pentacoordinate carbon in which 3 normal bonds and one bond partially formed with the nucleophile and one bond partially broken with the leaving group. It looks like a wheel with 3 leaves (3 bonds) on an axle(partial bonds).
Once the bond with LG is totally broken and bond with nucleophile is completely formed, it regains its tetrahedral stucture but with inversion.
It is called Walden inversion[ it can be described as the
umbrella going backwards in strong gale].
can someone show me how to do the work and explain it to me 9. A pentacoordinate carbon is a transient species in th...
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12. Which of the following does not correctly describe Sn2 reactions of alkyl halides? Tertiary halides react faster than secondary halides. Rate of reaction depends on the concentrations of both the alkyl halide and the nucleophile. The mechanism consists of a single step with no intermediates. The transition state species has a pentavalent carbon atom.
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8. Which of the following reacts fastest with methanol by the SNI mechanism? A) CH2CH2CH2CH2CH2Br B) CH2CH2CH2CHCH3 Br C) (CH3)2CCH2CH3 Br D) (CH3)3CCH2Br
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12. Which of the following does not correctly describe NZ he following does not correctly describe SN2 reactions of alkyl halides? B. Tertiary halides react faster than secondary halides. e or reaction depends on the concentrations of both the alkyl halide and the nucleophie. The mechanism consists of a single step with no intermediates. The transition state species has a penta valent carbon atom.
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0 IUINU nations favor the Snl mechanism as opposed to the Sn2 mechanism? I. tertiary alkyl halide II. primary alkyl halide III. polar solvent A. only 1 B. only II C. I and III D. II and III
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Which of the following is the rate law for the Syl mechanism of an alkyl halide with a nucleophile? rate = kalkyl halide] rate = k/nucleophile rate = kalkyl halide||nucleophile rate = k[alkyl halide nucleophile
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18. The species shown below represents the transition state for the: CH2CH3 HO ----C----- Br S HH A. reaction of 1-propanol with HBr. reaction of 1-bromopropane with OH". elimination of HBr from 1-bromopropane. addition of HBr to propene with peroxides. B. C.
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14. Which of the following reacts the slowest with sodium cyanide, NACN? OTs A) OTs B) D) OTs OTs
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10. What is the leaving group in the following reaction? CH,CHOH + HCI , CHCHCI + 0 А. ОН НО CH3CH, CI D.
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work ?
10. What is the leaving group in the following reaction? СНСЬCI + њо СНЫСЊOH + HCI ОН Н,0 CH3CH, СІ
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19. The species shown below represents the transition state for the: CH2CH3 H2O ----C----- Br 8+ 8 нн reaction of 1-propanol with HBr. reaction of 1-bromopropane with OH. addition of HOBr to 1-propene. addition of HBr to propene with peroxides.