
8. (4 points each) Complete the following two -NHNHA - 02 reduction 1) LIAIH, (excess) 2)...
8. (4 points each) Complete the following two NO2 -NHNH2 + V ON- reduction 1) LIAIH, (excess) 2) H30*
8. (4 points each) Complete the following two NO2 -ΝΗNH2 O2N- H Teduchion 1) LIAIH (excess) 2) H30*
23Dime PROTON 8. (4 points each) Complete the following two reactions, No2 reduction 1) LIATH, (excess) 2) H,09 (Major Organic Product) 9. (5 points) Complete the following reaction. Compare the stability of the organic starting material with the major organic product. Discuss the driving force(s) of this reaction. me ph howet v ph" 1. NaOH, HO NH2 2.HCI, H20 PN h
2) Draw the missing product(s) for each reaction: 2) H3O+ 1) NaBHA 2) H30* 1) LİAİH 2) H30+ 2) H30 1) CH2MgBr (excess) Page 1/3
Amine Reactivity Practice (1 of 3) Complete the following reactions: -NaOH- NH3 2 LiAIH 4 LIAIH4 CN
8. Write the product of the following reactions: [2x6=12] Br (1) NaNz (2) LiAIH (3) H2O* obvioblastod Br (1) NaCN (2) LiAIHA (3) H30 (b) NaNO2, HCI - I (c) H NH₂ (d) co, CHANH + CH3NH2 + bi- o-Nitroaniline 1. NaNO2, HCI, H2O 2. CuCN
5. Please predict the products from the following reaction sequence (10 points): 1. LiAIH 4 2. H 3. TsCl, pyridine CHO CHO
one and two
1. Aldehydes are more susceptible to nucleophilic attack than ketones. Explain. 2. Complete the following reaction scheme. РОCЬ pyridine 1. O3 NaBH 2. Me S E1OH (CH3)2CuLi SOC/2 H30*, heat 1. LIAIH NaCN Br 1. DIBALH acetone 2. Hа0 2. H30* 1. DIBALH 2. H30* HCN
Predict the product(s) for the following reaction. 1. excess LiAIH 2.H20 Edit Predict the product for the following reaction. 0 Br Mg/ether 1. H 1 H 2. H20 12 Edit Predict the major product for the following reaction. -OH 1. TsClipyridine 2. CH CH ONa 12 Edit Predict the product for the following reaction. NaH OH Br heat ? Edit
web. Please complete the following spiderweb involving the chemistry of carboxylic acid derivatives. Assume an excess of all reagents: if you need more than one equivalent of somet for you! Pay particular attention to the use of heat as a reagent. 1. CHỊ MgBr 2. H2O 1. CH-MOBI 2. H2O 1. LIAIH 2. H2O 1. CHgMgBr 2. H2O 1. LIAH 2. H2O H20 H2SO4 1. CO2 2. H30* NH2 (2 eq) CH3NH2 room temperature or heat 200 °C