Hi you have given me a lot of work and within allotted time it is not possible to analyze each and every thing, hence i am gonna give you a table of frequencies which is used to differentiate the 12 compounds here.
|
Alcohol |
|||
|
O-H |
(stretch, H-bonded) |
3200-3600 |
strong, broad |
|
O-H |
(stretch, free) |
3500-3700 |
strong, sharp |
|
C-O |
(stretch) |
1050-1150 |
strong |
|
Alkane |
|||
|
C-H |
stretch |
2850-3000 |
strong |
|
-C-H |
bending |
1350-1480 |
variable |
|
Alkene |
|||
|
=C-H |
stretch |
3010-3100 |
medium |
|
=C-H |
bending |
675-1000 |
strong |
|
C=C |
stretch |
1620-1680 |
variable |
|
Aromatic |
|||
|
C-H |
stretch |
3000-3100 |
medium |
|
C=C |
stretch |
1400-1600 |
medium-weak, multiple bands |
|
Nitrile |
|||
|
CN |
stretch |
2210-2260 |
medium |
|
Aldehyde |
|||
|
C=O |
stretch |
1740-1720 |
strong |
|
=C-H |
stretch |
2820-2850 & 2720-2750 |
medium, two peaks |
|
Amide |
|||
|
C=O |
stretch |
1640-1690 |
strong |
|
N-H |
stretch |
3100-3500 |
unsubstituted have two bands |
|
N-H |
bending |
1550-1640 |
|
|
Ester |
|||
|
C=O |
stretch |
1735-1750 |
strong |
|
C-O |
stretch |
1000-1300 |
two bands or more |
|
Ketone |
|||
|
acyclic |
stretch |
1705-1725 |
strong |
|
cyclic |
stretch |
3-membered - 1850 |
strong |
|
a,b-unsaturated |
stretch |
1665-1685 |
strong |
|
aryl ketone |
stretch |
1680-1700 |
strong |




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