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12. From each set of compounds select the compound with the highest vapor pressure. 1. Cl2 or Br2 II. HCl or HF III. HI or HB

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Answer #1

Ans: e = Cl2, HCl, HBr

Higher vapour pressure = weaker intermolecular forces = lower boiling point

Intermolecular force between molecules

Boiling point

(BP)

Higher BP due to

I

Cl2

Dispersion force

−34.04 °C

Higher vapor pressure

Br2

Dispersion force

58.8 °C

Heavier mass

II

HCl

Dipole-Dipole interaction

-85.05 °C

Higher vapor pressure

HF

Hydrogen bonding

19.5 °C

Stronger intermolecular force

III

HI

Dipole-Dipole interaction

-35.36 °C

Heavier mass

HBr

Dipole-Dipole interaction

-66 °C

Higher vapor pressure

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