Ans: e = Cl2, HCl, HBr
Higher vapour pressure = weaker intermolecular forces = lower boiling point
|
Intermolecular force between molecules |
Boiling point (BP) |
Higher BP due to |
|||
|
I |
Cl2 |
Dispersion force |
−34.04 °C |
Higher vapor pressure |
|
|
Br2 |
Dispersion force |
58.8 °C |
Heavier mass |
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|
II |
HCl |
Dipole-Dipole interaction |
-85.05 °C |
Higher vapor pressure |
|
|
HF |
Hydrogen bonding |
19.5 °C |
Stronger intermolecular force |
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|
III |
HI |
Dipole-Dipole interaction |
-35.36 °C |
Heavier mass |
|
|
HBr |
Dipole-Dipole interaction |
-66 °C |
Higher vapor pressure |
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