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Classify each structure according to its functional class. For parts C and D, also indicate if...

Classify each structure according to its functional class. For parts C and D, also indicate if the group is 1 degree, 2 degree, or 3 degree.

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Concepts and reason

The structures of several molecules are given and the functional groups need to be identified. The groups responsible for the characteristic chemical properties of a molecule are known as functional groups.

Fundamentals

Skeletal structure: The skeletal formula represents the bonding of different atoms with each other and shows the basic skeleton of the molecule.

The several groups that a molecule can possess are listed below:

• Alkyl halide: When a halogen is directly attached to carbon atom, then it is known as alkyl halide. They are represented as R-X, where R is an alkyl group and X represents halogen.

• Amine: It is represented as NH2 - {\rm{N}}{{\rm{H}}_2} .

• Carboxylic acid: It is represented as -COOH. It is shown as follows:

R
НО
H
Carboxylic acid

Where R is an alkyl group.

• Amide: It is represented as CONH2 - {\rm{CON}}{{\rm{H}}_2} . It is shown below:

NH2
R
Amide

Part A.

The functional group present in the molecule is carboxylic acid.

Carboxylic acid
Но

Part B

The functional group present in the molecule is alkyl halide.

Br
Alkyl halide

Part C

The functional group present in the molecule is amide (secondary).

Methyl
NH
Secondary amide

Part D

The functional group present in the molecule is amine (tertiary).

Ethyl
Tertiary amine
Ethyl
Isopropyl

Ans: Part A

Amide
Carboxylic acid
Amine
Alkyl halide

Part B

Amide
Carboxylic acid
Amine
Alkyl halide

Part C

1° (Primary Amide)
Amide
20 (Secondary Amide)
Carboxylic acid
3° (Tertiary Amide)
Amine
Alkyl halide

Part D

1° (Primary Amine)
Amide
20 (Secondary Amine)
Carboxylic acid
30 (Tertiary Amine)
Amine
Alkyl halide

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