Question

Give the structures of the major organic products you would expect from reaction of m-toluidine (m-methylaniline)...

Give the structures of the major organic products you would expect from reaction of m-toluidine (m-methylaniline) with the following reagents:
(a) Br2 (1 equivalent) (b) CH3I (excess)
(c) CH3COCl in pyridine (d) The product of (c) then HSO3Cl
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Answer #1

(a) In m-toluidine, both -NH2 and -CHs are ring activating groups. So, they direct the incoming electrophile to attack at the

(b) Treatment of amines with excess CH3I is exhaustive methylation where a tertiary amine is produced The reaction is as foll

The reaction is as follows: NH CH3 CH3COCI pyridine CH CH3 N-(m-tolyl)acetamide (d) The product of (c) is N-(m-tolyl) acetami

The reaction is as follows: NH CH NH CH HSO3C CH 3 CH3 So C 4-acetamido-2-methylbenzene-1-sulfonyl chloride

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