What is the boiling point in ∘C of each of the solutions below? For water, Kb = 0.51(∘C ⋅ kg)/mol.
A solution of 15.0 g of LiCl in 158.0 g of water at 45.0 ∘C, assuming complete dissociation.
Using, Tb - Tb° = i×Kb×m
Where Tb is boiling point of solution
Tb° is boiling point of pure water = 100 °C
Kb = 0.51 °C.Kg/mol
i = 2 = number of ions formed after dissociation
Molality, m = mass of LiCl×1000/molar mass×mass of water
= 15×1000/158×42.394
= 2.239 m
Now, Tb = Tb° + i×Kb×m
= 100 + 2×0.51×2.239
= 100 + 2.284
= 102.28 °C
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