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When 1,5-dibromopentane reacts with ammonia, among several products isolated is a water-soluble compound A that rapidly...

When 1,5-dibromopentane reacts with ammonia, among several products isolated is a water-soluble compound A that rapidly gives a precipitate of AgBr with acidic AgNO3 solution. Compound A is unchanged when treated with dilute base, but treatment of A with concentrated NaOH and heat gives a new compound B (C10H19N) that decolorizes Br2 in CCl4. Compound B is identical to the product obtained from the reaction sequence shown below. Identify A and B.


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Answer #3

A= CH2(NH2)-CH2-CH2-CH2-CH2Br

B = CH2=CH-CH2-CH2-CH2-NH-CH2-CH2-CH2-CH=CH2

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