Question

Alkenes can be converted to alcohols by reaction with mercuric acetate to form a ?-hydroxyalkylmercury(II) acetate compound, a reaction called oxymercuration. Subsequent reduction with NaBH4 reduces the C?Hg bond to a C?H bond, forming the alkyl alcohol, a reaction called demercuration. Draw the structures of the Hg-containing compound(s) and the final alcohol product(s) formed in the following reaction sequence, omitting, by products. If applicable, draw hydrogen at a chirality center and indicate stereochemistry via wedge-and-dash bonds.


Neutral produst (s) of oxymercuration. Include stereoisomers, if any

image from custom entry tool HG(OOCCH3)2

----------------->

H2O,THF





Alcohol product (s) of demercuration. Include stereoisomers, if any



NaBH4

------->

HO-







Select all that apply: The alcohol product(s) of the reaction is characterized as being


_____ R,R

_____ R,S (and/or S,R)

_____ S,S

_____ achiral

_____ racemic

_____ diastereomers

_____ R

_____ S

Answer 1

In organic chemistry, an alkene, olefin, or olefine is an unsaturated chemical compound containing at least one carbon-to-carbon double bond.[1] The simplest acyclic alkenes, with only one double bond and no other functional groups, form an homologous series of hydrocarbons with the general formula CnH2n.[2]
The simplest alkene is ethylene (C2H4), which has the International Union of Pure and Applied Chemistry (IUPAC) name ethene. Alkenes are also called olefins (an archaic synonym, widely used in the petrochemical industry). For bridged alkenes, the Bredt's rule states that a double bond cannot be placed at the bridgehead of a bridged ring system, unless the rings are large enough. Aromatic compounds are often drawn as cyclic alkenes, but their structure and properties are different and they are not considered to be alkenes.

Answer 2

Answer 3

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