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e : ed3114#10001 14 01 25 Review | Constants Periodic Table Part A Predict the cation-anion distance using the values of ioni
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Answer #1

Part.A. Sol :-

(a). LiF :-

Ionic radius of Li+ cation = 0.68 Å

Ionic radius of F- anion = 1.33 Å

Therefore,

Distance between cation and anion in LiF = dLi+F- =  Ionic radius of Li+ cation + Ionic radius of F- anion

= 0.68 Å + 1.33 Å

= 2.09 Å

Hence, dLi+F- = 2.09 Å

-------------------------

(b). NaCl :-

Ionic radius of Na+ cation = 1.16 Å

Ionic radius of Cl- anion = 1.67 Å

Therefore,

Distance between cation and anion in NaCl = dNa+Cl-=  Ionic radius of Na+ cation + Ionic radius of Cl- anion

= 1.16 Å + 1.67 Å

= 2.83 Å

Hence, dNa+Cl- = 2.83 Å

-------------------------

(c). KBr :-

Ionic radius of K+ cation = 1.52 Å

Ionic radius of Br- anion = 1.82 Å

Therefore,

Distance between cation and anion in KBr = dK+Br-=  Ionic radius of K+ cation + Ionic radius of Br- anion

= 1.52 Å + 1.82 Å

= 3.34 Å

Hence, dK+Br- = 3.34 Å

-------------------------

(d). RbI :-

Ionic radius of Rb+ cation = 1.66 Å

Ionic radius of I- anion = 2.06 Å

Therefore,

Distance between cation and anion in RbI= dRb+I-=  Ionic radius of Rb+ cation + Ionic radius of I- anion

= 1.66 Å + 2.06 Å

= 3.72 Å

Hence, dRb+I- = 3.72 Å

-------------------------

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