The formation of high-molecular-weight olefins, for example,
Time (min) | 0 | 2.1 | 3.75 | 6.0 | 8.2 | 11.4 ‘ | 15.4 | 20.4 | 25.7 | 28.4 | 31.0 |
T (°C) | 18.0 | 21.5 | 25.5 | 30.7 | 36.0 | 39.5 | 42.5 | 46.8 | 52.53 | 57.1 | 62.3 |
Time (min) | 33.2 | 34.45 | 35.2 | 35.8 | 36.8 | 37.2 | 37.8 | 38.0 | 38.2 | 38.0 | 40.6 |
reo | 68.8 | 74.2 | 78.3 | 82.8 | 94.0 | 103.8 | 125.3 | 142.3 | 157.0 | 166.8 | 164.6 |

is carried out in the CSTR shown in Figure P9-20D(a) where (=) denotes the molecule is an olefin. The reaction is exothermic, and heat is removed from the reactor by heat exchange with a cooling water stream as shown in Figure P9-20D(a).
Troubleshooting

Initially, there is a temperature controller that regulates the reactor temperature. At t = t1 the controller is set into manual, and a step increase in the water flow rate through the heat exchanger was made. The temperature response is shown in Figure P9-20D(b). What are the parameters to match this trend?
Explain the observed temperature-time trajectory. To make your analysis simpler, you may assume that the only reaction taking place is
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With
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Also, you can assume that the exchanger is inside the reactor (to avoid recycle stream calculations). See P9-20 CD-ROM Complete Data Set.
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