Solution 1:
| Options | Annuity Payment | Annuity Factor | PV annuity | Immediate Cash | PV Option | ||
| Option 1 | $0.00 | 0 | $0 | + | $86,000 | = | $86,000 |
| Option 2 | $9,200.00 | 4.91732 | $45,239 | + | $32,000 | = | $77,239 |
| Option 3 | $17,400.00 | 4.91732 | $85,561 | + | $0 | = | $85,561 |
| Which Option Alex should choose | Option 1 | ||||||
Solution 2:
| Table or calculator function | Future value of an ordinary annuity of $1 |
| Payment | $170,000.00 |
| n= | 10 |
| i= | 7% |
| Annuity factor | 13.8164 |
| Future value | $2,348,788.00 |
TABLE 1 Future Value of $1 FV= $1 (1 + ir n/i 5.5% 1 1.01000 1.01500...
TABLE 1 Future Value of $1 FV= $1 (1 + ir n/i 5.5% 1 1.01000 1.01500 1.02000 1.02500 1.03000 1.03500 1.04000 1.04500 1.05000 1.05500 1.06000 1.07000 .08000 1.09000 1.10000 1.11000 1.12000 .20000 2 1.02010 1.03022 1.04040 1.05063 1.06090 1.07123 1.08160 1.09203 1.10250 1.11303 1.12360 1.14490 .16640 1.18810 1.21000 1.23210 1.25440 144000 3 1.03030 1.04568 1.06121 1.07689 1.09273 1.10872 1.12486 1.14117 1.15763 1.17424 1.19102 1.22504 .25971 29503 1.33100 1.36763 1.40493 .72800 4 1.04060 1.06136 1.08243 1.10381 1.12551 1.14752 1.16986 1.19252 1.21551...
analyze this NMR & IR
S23 CDC13 QE-300 240 UN (43 MIL.) 10.02s, 1H), 7.716.J-2 Hz. ) 2.0 11.5 11.0 10.5 10.0 9.5 9.0 8.5 8.0 7.5 7.0 6.5 6.0 4.0 3.5 3.0 2.5 20 15 100.5 0.0 -0.5 -1.0 -1.5 -2. 5.5 5.0 4.5 fl (ppm)
A variety of spectra for an organic compound with molecular
formula C10H16O are presented below. The
experimental accurate mass using (+) APCI source is 153.1280 u. The
1H, 13C, COSY, HSQC and HMBC NMR spectra are given in the following
slides. Propose a structure for this unknown and answer or address
the following questions or requirements:
d. If there are still any questionable assignments, propose
additional NMR experiments which would solve those questions and
briefly explain specifically what correlations you...
Boxes Task: Evaluate whether you can load various sizes of jars into boxes. For each test, you will input the length, width, and height of a box as well as the diameter and height of a cylindrical jar. The algorithm will determine whether each jar will fit in its corresponding box. The jar can sit upright in the box, or it can lie on its side with its top parallel to one of the sides of the box. Assume that...
Fill out the tables below of the starting material and pure
product by using the given NMR spectrums. Identify if the pure
isomer of methyl nitrobenzoate as ortho, meta, or para.
Complete the table below using your proton NMR spectrum of your starting material. Be sure to include all peaks. Note: The table is expandable. Use the structure below for the letter assignments in your table. Splitting Integration Assignment Peak (ppm) Other Notes -7.95 -7.92 0627 -787 785 7.30 751...
A variety of spectra for an organic compound with molecular
formula C10H16O are presented below. The
experimental accurate mass using (+) APCI source is 153.1280 u. The
1H, 13C, COSY, HSQC and HMBC NMR spectra are given in the following
slides. Propose a structure for this unknown and answer or address
the following questions or requirements:
a. Using the most abundant isotopes of C, H and O, what are the
errors in ppm and milli-Daltons for the experimental accurate
mass?...
Below are four bivariate data sets and the scatter plot for each. (Note that each scatter plot is displayed on the same scale.) Each data set is made up of sample values drawn from a population. x y 1.0 4.1 2.0 6.1 3.0 7.0 4.0 4.0 5.0 5.2 6.0 8.1 7.0 5.5 8.0 6.9 9.0 9.0 10.0 7.3 x1234567891011y12345678910110 Figure 1 u v 1.0 8.1 2.0 7.4 3.0 8.1 4.0 6.1 5.0 7.4 6.0 4.5 7.0 4.6 8.0 3.4...
7. What kind of carbons correspond to these chemical
shifts?
8. Based on this analysis, the unknown might contain the
following substructure:
UN (43 MIL.) 10.02s, 1H), 7.716.J-2 Hz. ) 2.0 11.5 11.0 10.5 10.0 9.5 9.0 8.5 8.0 7.5 7.0 6.5 6.0 4.0 3.5 3.0 2.5 20 15 100.5 0.0 -0.5 -1.0 -1.5 -2. 5.5 5.0 4.5 fl (ppm)
How would you analyze the peaks for a 1H NMR of
Bromovanillyl Alcohol and an IR spectra of Bromovanillyl
Alcohol?
IR Peaks
NMR Peaks
%Transmittance 3446.63 3121.86 8 3004.87 2925.69 2877.64 8 1611.72" 1588.93 1499.44 1420.46 1398.31 1371.05 05 1277.51 1200.01 1179.94 1143.10 8 1047.61 1010.21 948.66 852.87 836.91 823.94 780.44 719.71 H NMR (400 mHz, CDCls) Br 6.86 s) 92 7.09 5.90 4.60 1.64 CDCls H20 12.5 12.0 11.5 11.0 10.5 10.0 9.5 9.0 8.5 8.0 7.5 7.0 6.5...
5. Based on this analysis, the compound might be or contain
the following substructure:
6. How many different types of carbons appear to be present?
What are the chemical shifts for these carbons?
UN (43 MIL.) 10.02s, 1H), 7.716.J-2 Hz. ) 2.0 11.5 11.0 10.5 10.0 9.5 9.0 8.5 8.0 7.5 7.0 6.5 6.0 4.0 3.5 3.0 2.5 20 15 100.5 0.0 -0.5 -1.0 -1.5 -2. 5.5 5.0 4.5 fl (ppm)