
2. For 2a - 2j. predict the product or products for the following reactions. If no...
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2. For 2a-2j, predict the product or products for the following reactions. If no reaction occurs for the given conditions write no reaction and explain why there is no reaction. You must indicate the correct stereochemistry where needed in order to get full credit. (3 points each) NOTE: any carbon atom with a start next to it ( C*) indicates that this Carbon atom can be in either the R-or S- absolute configuration. 2a. 1. 2 mol O...
2. For 2 -2. predict the product or products for Occurs for the given conditions write You must indicate the correct stereochemistry w points each) ere is no reaction. ons write no reaction and explain why there is no acts for the following reactions. If no reaction were needed in order to get full credit NOTE: any carbon atom be in either the R tom with a start next to it S indicates that this Carbon -absolute configuration. ates that...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
CHEM 2343A HOMEWORK W13 Name: DUE 11/18/19 at 9:10 AM There are total of 4 questions on this homework assignment 1. For the reaction outlined below in la and I draw out the reaction mechanism using arrow formalism to describe how the reaction below occurs. Be sure to draw out all action intermediates & the moment of all electrons needed to justify the formation of the indicand product. You do not need to add in any reagents that are not...
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2. Complete the following reactions with correct stereochemistry (4 points) 1. Sia BH 1. =co Na 2. H2O2, NaOH 2. H30* Na, NH3 ti, na mCPBA correct stereochemistry correct stereochemistry
Give the missing reagent(s). Matching H2SO., H30 Cl2 1) Br, H;O 2) NaH KMnO Cold, Dilute,Basic HCI 1) BH THE 2) H2O2, OH 1) Hg(OAc), H:0 2) NaBH, OH 1) Os 2) (CH3)2S H20, H SO. mCPBA 1) mCPBA 2) H30 Na. 1) OsO. 2) NaHSO; Liquid NH; 1) mCPBA 2) H30, OH Lindlar's Catalyst
1. Give the structure(s) of the major product(s) expected from the following reactions. Assume standard aqueous workup conditions are used for product isolation. (40 points, 4 points for cach). H a) Sia,BH (1.0 eq) THF, 0 °C b) CH-CO-D, 60 °C OTS KOI-Bu -BuOH "Me 1a, LDA (1.0 eq). THF, -78 °C 16. TMSCI 2a, Toluene, heat 2b, H* acequous workup 1a, LDA, THF 2, LDA (1.0 q). THE 10. CH3COCI 2, CH,CH_CH_Br EtOC 1) HCI, MeOHXH, heat 2). Hz,...
" LU PUMPS 1. Draw the major product formed from the following elimination reactions. (4 pts) NaOEt EtOH, heat 85% H3PO4 80° C heat Y + t-BuOKA-BOH EtOH + NaOEt 55°C - Complete the following reactions with correct stereochemistry (4 points) 1. Sia BH 1. =co Na 2 H₂Oh 2. H2O2, NaOH Na NH3 mCPBA Line- correct stereochemistry correct stereochemistry
s) Predict the principal organic product(s) in each of the following reactions. Draw the correct stereoisom wherever applicable (Structures with incomplete/wrong stereochemistry will not be accepted!!). CH₃ Clz Br2 Н,0 CCIA 1) BH3. THE 2) H2Oz/NaOH 1) O₃ 2) (CH3)2S МСРВА MCPECIES CH2Cl2 OsO4 NMO 1) МСРВА 2) H2O/H30* Hoy for Hos 1) Brz/H20 2) NaOH 1) Hg(OAC)2, H2O/THF 2) NaBHA = 1) O₃ 2) H20 340 H2SO4 HgSO4 2 Brz CCIA 2 HCI 26. pts) Listed below is information...
Predict the products of the following reactions.
Na, NH3 1 equivalent HBr f. Br NaNH2 (excess) Br g. 1. Sia BH, THF 2. H202, NaOH h. HgSO HSO HO I